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Chemistry: Recent submissions
Now showing items 201-220 of 964
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A polarographic study of alpha- and beta-angelicalactone
(University of Kansas, 1948) -
KU’s First Woman of Chemistry, Mary Elvira Weeks, A History of Our Historian
(University of Kansas, Department of Chemistry, 1999)Mary Elvira Weeks (1892–1975) was the first woman to earn a PhD in chemistry at the University of Kansas and the first woman on the chemistry faculty there (1921–1944), attaining the rank of associate professor in 1937. ... -
A. The mercuration of diphenyl ether and some of its derivatives.B. Derivatives of sulfanilamide
(University of Kansas, 1941) -
Mechanisms of epoxide reactions
(University of Kansas, 1949) -
I. Polarographic behavior of simple chlorinated organosilanesII. Polarographic investigations in pyridine
(University of Kansas, 1951) -
Studies on nicotinamide
(University of Kansas, 1949) -
Using Fluorescence Derivatization and Analytical Separations to Investigate Biomarkers of Oxidative Stress
(University of Kansas, 2017-08-31)Oxidative stress occurs when there is an overproduction of reactive nitrogen and oxygen species in the body. This condition has been linked to many prominent diseases. This thesis details analytical methods that use ... -
Palladium-Catalyzed Synthesis and Racemization of Conjugated Allenynes
(University of Kansas, 2017-08-31)Allenes are structurally unique compounds that can possess axial chirality. The most common strategy for allene synthesis is transition metal-catalyzed cross coupling with propargyl electrophiles. While these are powerful ... -
Development of Separation-Based Microfluidic Platforms to Study Intracellular Nitrosative and Oxidative Stress
(University of Kansas, 2017-08-31)Nitrosative and oxidative stress are conditions caused by the overproduction of reactive nitrogen and oxygen species (RNOS), respectively. Nitric oxide (NO) and superoxide (O2•−) are the main sources of all RNOS. Macrophages ... -
Probing complex electron dynamics in multieclecton atoms and one electron molecule ion in presence of ultra short laser pulse
(University of Kansas, 2017-08-31)We performed an ab initio and accurate exploration of complex electron dynamics in multieclecton atoms and one electron molecule ion in presence of ultra short laser pulse. Particularly, an ab initio 3D precision calculation ... -
Reorientation Dynamics of Branched and Linear Alcohols
(University of Kansas, 2017-08-31)Molecular reorientation of the four isomeric butanols are investigated with molecular dynamics simulations. The purpose of this study is to probe how alcohol reorientational and hydrogen-bond (H-bond) dynamics is influenced ... -
Synthesis and Characterization of Amide and Urea Receptor Systems for Anion and Metal Complexation and the Synthesis and Use of Block Copolymers for Optoelectronic Crystal Growth
(University of Kansas, 2017-08-31)The content of this dissertation is divided into two parts, as a result of projects from two research groups during the course of my research at the University of Kansas. The first five chapters detail my work with Dr. ... -
High-Throughput Screening (HTS) of Potential Lead Compounds for Target Proteins with No False Identifications Using LC/MS
(University of Kansas, 2017-08-31)Developing effective high throughput screening (HTS) methods is of paramount importance in the early stage of drug discovery. When a protein binding event can be detected via spectroscopy, then absorbance, fluorescence or ... -
Single Molecule Analysis of Biomembrane Heterogeneity
(University of Kansas, 2017-08-31)The biological membrane is a complex and dynamic structure that participates in many important cellular functions. As such, model membranes are frequently employed to study membrane structure and its relationship to function. ... -
On Bilayer Deformation Energetics With and Without Gramicidin A Channel
(University of Kansas, 2017-08-31)Lipid membranes are not simply passive barriers. Embedded proteins are coupled to the membrane and can deform the surrounding bilayer, which incurs an energetic penalty. To minimize these penalties, proteins are known to ... -
Regiodivergent condensation of 5-alkoxycarbonyl-1H-pyrrol-2,3-diones with cyclic ketazinones en route to spirocyclic scaffolds
(Beilstein, 2017-10-19)The condensation of 5-alkoxycarbonyl-1H-pyrrolediones with cyclic ketazinones was systematically investigated. It was discovered that the regioselectivity of this reaction can be easily swapped between two alternative ... -
Accurate Assignments of Excited-State Resonance Raman Spectra: A Benchmark Study Combining Experiment and Theory
(American Chemical Society, 2017-09-27)Femtosecond stimulated Raman scattering (FSRS) probes the structural dynamics of molecules in electronically excited states by following the evolution of the vibrational spectrum. Interpreting the dynamics requires accurate ... -
Directed Rh(I)-Catalyzed Asymmetric Hydroboration of Prochiral 1-Arylcycloprop-2-ene-1-carboxylic Acid Derivatives
(Wiley, 2017-12-19)A full account on rhodium-catalyzed asymmetric, directed hydroboration of functionalized prochiral cyclopropenes affording enantiomerically enriched cyclopropylboronates is reported. The scope and limitations of two alternate ... -
A study of some polarization effects in aromatic ethers
(University of Kansas, 1943) -
The determination of ion transference in solutions of electrolytes in anhydrous acetic acid
(University of Kansas, 1938)