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Anodic Oxidation of m-terphenyl thio-, seleno-and telluroethers: Lowered oxidation potentials due to chalcogen.•••π interaction
| dc.contributor.author | Wilson, George S. | |
| dc.contributor.author | Ammam, Malika | |
| dc.contributor.author | Zakai, Uzma I. | |
| dc.contributor.author | Glass, Richard S. | |
| dc.date.accessioned | 2011-11-18T19:58:30Z | |
| dc.date.available | 2011-11-18T19:58:30Z | |
| dc.date.issued | 2010-02 | |
| dc.identifier.citation | Ammam, M., Zakai, U.I., Wilson, G.S., Glass, R.S., Anodic Oxidation of m-terphenyl thio-, seleno-and telluroethers: Lowered oxidation potentials due to chalcogen.•••π interaction,. Pure and Applied Chemistry, 82, 555-563 (2010) | |
| dc.identifier.uri | http://hdl.handle.net/1808/8416 | |
| dc.description.abstract | The electrochemistry of m-terphenylthio-, seleno-, and telluroethers was studied using cyclic voltammetry in acetonitrile. All of the compounds studied showed irreversible oxidations. The first oxidation potentials for the thio- and selenoethers are less positive than expected. This facilitation in oxidation is ascribed to through-space S···π and Se···π interaction, respectively, on removal of an electron. No evidence for a comparable effect was found for the phenyltelluro-ethers studied. | |
| dc.language.iso | en_US | |
| dc.publisher | International Union of Pure and Applied Chemistry | |
| dc.relation.isversionof | http://www.iupac.org/publications/pac/pdf/2010/pdf/8203x0555.pdf | |
| dc.title | Anodic Oxidation of m-terphenyl thio-, seleno-and telluroethers: Lowered oxidation potentials due to chalcogen.•••π interaction | |
| dc.type | Article | |
| kusw.kuauthor | Wilson, George S. | |
| kusw.kudepartment | Chemistry | |
| kusw.oastatus | fullparticipation | |
| kusw.oaversion | Scholarly/refereed, publisher version | |
| kusw.oapolicy | This item meets KU Open Access policy criteria. | |
| dc.rights.accessrights | openAccess |
