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    Anodic Oxidation of m-terphenyl thio-, seleno-and telluroethers: Lowered oxidation potentials due to chalcogen.•••π interaction

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    Wilson_2010_Anodic Oxidation of m-terphenyl thio.pdf (256.5Kb)
    Issue Date
    2010-02
    Author
    Wilson, George S.
    Ammam, Malika
    Zakai, Uzma I.
    Glass, Richard S.
    Publisher
    International Union of Pure and Applied Chemistry
    Type
    Article
    Article Version
    Scholarly/refereed, publisher version
    Published Version
    http://www.iupac.org/publications/pac/pdf/2010/pdf/8203x0555.pdf
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    Abstract
    The electrochemistry of m-terphenylthio-, seleno-, and telluroethers was studied using cyclic voltammetry in acetonitrile. All of the compounds studied showed irreversible oxidations. The first oxidation potentials for the thio- and selenoethers are less positive than expected. This facilitation in oxidation is ascribed to through-space S···π and Se···π interaction, respectively, on removal of an electron. No evidence for a comparable effect was found for the phenyltelluro-ethers studied.
    URI
    http://hdl.handle.net/1808/8416
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    • Chemistry Scholarly Works [610]
    Citation
    Ammam, M., Zakai, U.I., Wilson, G.S., Glass, R.S., Anodic Oxidation of m-terphenyl thio-, seleno-and telluroethers: Lowered oxidation potentials due to chalcogen.•••π interaction,. Pure and Applied Chemistry, 82, 555-563 (2010)

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    Contact KU ScholarWorks
    785-864-8983
    KU Libraries
    1425 Jayhawk Blvd
    Lawrence, KS 66045
    785-864-8983

    KU Libraries
    1425 Jayhawk Blvd
    Lawrence, KS 66045
    Image Credits
     

     

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