“Click”-Capture, ROMP, Release: Facile Triazolation Utilizing ROMP-derived Oligomeric Phosphates

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Issue Date
2011-04-15
Author
Long, Toby R.
Faisal, Saqib
Maity, Pradip K.
Rolfe, Alan
Kurtz, Ryan D.
Klimberg, Sarra V.
Majjar, Muhammad-Rabbie
Basha, Fatima Z.
Publisher
American Chemical Society
Type
Article
Article Version
Scholarly/refereed, author accepted manuscript
Rights
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/ol200430c
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Abstract
Soluble, high-load ROMP-derived oligomeric triazole phosphates (OTP) are reported for application as efficient triazolating reagents of nucleophilic species. Utilizing a “Click”-capture, ROMP, release protocol, the efficient and purification free, direct triazolation of N-, O- and S-nucleophilic species was successfully achieved. A variety of OTP derivatives were rapidly synthesized as free-flowing solids on multi-gram scale from commercially available materials.
URI
http://hdl.handle.net/1808/23358
DOI
https://doi.org/10.1021/ol200430c
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Citation
Long, T. R., Faisal, S., Maity, P. K., Rolfe, A., Kurtz, R., Klimberg, S. V., … Hanson, P. R. (2011). “Click”-Capture, ROMP, Release: Facile Triazolation Utilizing ROMP-derived Oligomeric Phosphates. Organic Letters, 13(8), 2038–2041. http://doi.org/10.1021/ol200430c

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