Facile assembly of 1,5-diazocan-2-ones via cyclization of tethered sulfonamides to cyclopropenes

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Issue Date
2020-12-15
Author
Matheny, Jonathon P.
Yamanushkin, Pavel M.
Petillo, Peter A.
Rubin, Michael
Publisher
Royal Society of Chemistry
Type
Article
Article Version
Scholarly/refereed, publisher version
Rights
© The Royal Society of Chemistry 2020. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
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Abstract
The sulfonamide moiety was evaluated as an activating and stabilizing functional group in the metal-templated strain release-driven intramolecular nucleophilic addition of amines to cyclopropenes to generate 1,5-diazocan-2-ones.
URI
http://hdl.handle.net/1808/33540
DOI
https://doi.org/10.1039/D0RA09014J
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Citation
Matheny, J.P.; et al. Facile assembly of 1,5-diazocan-2-ones via cyclization of tethered sulfonamides to cyclopropenes. RSC Adv., 2020,10, 44183-44190. https://doi.org/10.1039/D0RA09014J

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© The Royal Society of Chemistry 2020. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Except where otherwise noted, this item's license is described as: © The Royal Society of Chemistry 2020. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.