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dc.contributor.authorEdwards, Andrew
dc.contributor.authorRubina, Marina
dc.contributor.authorRubin, Michael
dc.identifier.citationA. Edwards, M. Rubina, M. Rubin, Chem. Eur. J. 2018, 24, 1394.en_US
dc.descriptionThis is the peer reviewed version of the following article: A. Edwards, M. Rubina, M. Rubin, Chem. Eur. J. 2018, 24, 1394., which has been published in final form at This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.en_US
dc.description.abstractA full account on rhodium-catalyzed asymmetric, directed hydroboration of functionalized prochiral cyclopropenes affording enantiomerically enriched cyclopropylboronates is reported. The scope and limitations of two alternate directing groups, ester and carboxamide, are evaluated. It was found that hydroboration of esters appeared to be more sensitive to substitution in the aromatic ring of the substrates. Specifically, ortho-halogens were detrimental for diastereo- and enantioselectivity, possibly because of additional coordination with rhodium. In contrast, more Lewis-basic amide directing groups allowed for stronger chelation to the transition metal, leading to consistently high diastereo- and enantioselectivity in hydroboration across a broader range of substrates.en_US
dc.rights© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.en_US
dc.titleDirected RhI-Catalyzed Asymmetric Hydroboration of Prochiral 1-Arylcycloprop-2-Ene-1-Carboxylic Acid Derivativesen_US
kusw.kuauthorEdwards, Andrew
kusw.kuauthorRubina, Marina
kusw.kuauthorRubin, Michael
kusw.oanotesPer Sherpa Romeo 08/19/2021:

Chemistry - A European Journal [Open panel below]Publication Information TitleChemistry - A European Journal [English] ISSNs Print: 0947-6539 Electronic: 1521-3765 URL Publishers Wiley [Commercial Publisher] Asian Chemical Editorial Society (ACES) [Associate Organisation] ChemPubSoc Europe [Associate Organisation] [Open panel below]Publisher Policy Open Access pathways permitted by this journal's policy are listed below by article version. Click on a pathway for a more detailed view.

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NoneCC BY-NC-NDPMC Any Website, Journal Website, +3 Accepted Version 12m Non-Commercial Institutional Repository, PMC, arXiv, +5 Embargo12 Months Location Author's Homepage Named Repository (arXiv, AgEcon, PhilPapers, PubMed Central, RePEc, SSRN) Non-Commercial Institutional Repository Conditions Publisher source must be acknowledged with citation Must link to publisher version with set statement (see policy) and DOI
kusw.oaversionScholarly/refereed, author accepted manuscripten_US
kusw.oapolicyThis item meets KU Open Access policy criteria.en_US

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