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Metal-Incorporated Mesoporous Silicates: Tunable Catalytic Properties and Applications

dc.contributor.authorRamanathan, Anand
dc.contributor.authorSubramaniam, Bala
dc.date.accessioned2019-11-25T14:34:36Z
dc.date.available2019-11-25T14:34:36Z
dc.date.issued2018-01-29
dc.identifier.citationRamanathan, A.; Subramaniam, B. Metal-Incorporated Mesoporous Silicates: Tunable Catalytic Properties and Applications. Molecules 2018, 23, 263.en_US
dc.identifier.urihttp://hdl.handle.net/1808/29803
dc.description.abstractA relatively new class of three-dimensional ordered mesoporous silicates, KIT-6, incorporated with Earth-abundant metals such as Zr, Nb, and W (termed as M-KIT-6), show remarkable tunability of acidity and metal dispersion depending on the metal content, type, and synthetic method. The metal-incorporation is carried out using one-pot synthesis procedures that are amenable to easy scale-up. By such tuning, M-KIT-6 catalysts are shown to provide remarkable activity and selectivity in industrially-significant reactions, such as alcohol dehydration, ethylene epoxidation, and metathesis of 2-butene and ethylene.We review how the catalytic properties of M-KIT-6 materials may be tailored depending on the application to optimize performance.en_US
dc.description.sponsorshipjoint National Science Foundation and Environmental Protection Agency program Networks for Sustainable Material Synthesis and Design (NSF-EPA 1339661)en_US
dc.description.sponsorshipthe National Science Foundation (OIA-1539105).en_US
dc.publisherMDPIen_US
dc.rights© 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).en_US
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/en_US
dc.subjectZirconiumen_US
dc.subjecttungstenen_US
dc.subjectniobiumen_US
dc.subjectLewis aciden_US
dc.subjectmesoporous silicaen_US
dc.subjectdehydrationen_US
dc.subjectepoxidationen_US
dc.subjectmetathesisen_US
dc.titleMetal-Incorporated Mesoporous Silicates: Tunable Catalytic Properties and Applicationsen_US
dc.typeArticleen_US
kusw.kuauthorSubramaniam, Bala
kusw.kudepartmentChemical and Petroleum Engineeringen_US
dc.identifier.doi10.3390/molecules23020263en_US
dc.identifier.orcidhttps://orcid.org/0000-0001-9462-7987en_US
kusw.oaversionScholarly/refereed, author accepted manuscripten_US
kusw.oapolicyThis item meets KU Open Access policy criteria.en_US
dc.rights.accessrightsopenAccessen_US


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© 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
Except where otherwise noted, this item's license is described as: © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).