Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri-annulations: efficient synthesis of 1,3,6,8-tetraazapyrenes
| dc.contributor.author | Aksenov, Alexander V. | |
| dc.contributor.author | Ovcharov, Dmitrii S. | |
| dc.contributor.author | Aksenov, Nicolai A. | |
| dc.contributor.author | Aksenov, Dmitrii A. | |
| dc.contributor.author | Nadein, Oleg N. | |
| dc.contributor.author | Rubin, Michael | |
| dc.date.accessioned | 2018-11-12T20:29:33Z | |
| dc.date.available | 2018-11-12T20:29:33Z | |
| dc.date.issued | 2017-06-08 | |
| dc.identifier.citation | Aksenov, A. V., Ovcharov, D. S., Aksenov, N. A., Aksenov, D. A., Nadein, O. N., & Rubin, M. (2017). Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri-annulations: efficient synthesis of 1, 3, 6, 8-tetraazapyrenes. RSC Advances, 7(48), 29927-29932. | en_US |
| dc.identifier.uri | http://hdl.handle.net/1808/27300 | |
| dc.description.abstract | A highly efficient synthetic method for expeditious and selective assembly of tetraazopyrenes (TAPy) is reported, based on the novel reaction of electrophilically activated nitroalkanes with aromatic amines. Remarkably, the nitroalkanes play a dual role in this process, also serving as mild and efficient oxidants promoting aromatization of the final product and allowing for the exclusion of a poorly controllable aerobic treatment. | en_US |
| dc.publisher | Royal Society of Chemistry | en_US |
| dc.rights | © The Royal Society of Chemistry 2017. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. | en_US |
| dc.rights.uri | https://creativecommons.org/licenses/by-nc/3.0/us/ | en_US |
| dc.title | Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri-annulations: efficient synthesis of 1,3,6,8-tetraazapyrenes | en_US |
| dc.type | Article | en_US |
| kusw.kuauthor | Rubin, Michael | |
| kusw.kudepartment | Chemistry | en_US |
| dc.identifier.doi | 10.1039/C7RA04751G | en_US |
| kusw.oaversion | Scholarly/refereed, publisher version | en_US |
| kusw.oapolicy | This item meets KU Open Access policy criteria. | en_US |
| dc.rights.accessrights | openAccess | en_US |
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