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dc.contributor.authorTang, Yu
dc.contributor.authorLi, Yuting
dc.contributor.authorFung, Victor
dc.contributor.authorJiang, De-en
dc.contributor.authorHuang, Weixin
dc.contributor.authorZhang, Shiran
dc.contributor.authorIwasawa, Yasuhiro
dc.contributor.authorSakata, Tomohiro
dc.contributor.authorNguyen, Luan
dc.contributor.authorZhang, Xiaoyan
dc.contributor.authorFrenkel, Anatoly I.
dc.contributor.authorTao, Franklin Feng
dc.date.accessioned2018-06-13T16:45:59Z
dc.date.available2018-06-13T16:45:59Z
dc.date.issued2018-03-26
dc.identifier.citationTang, Y., Li, Y., Fung, V., Jiang, D., Huang, W., Zhang, S., … Tao, F. (Feng). (2018). Single rhodium atoms anchored in micropores for efficient transformation of methane under mild conditions. Nature Communications, 9, 1231. http://doi.org/10.1038/s41467-018-03235-7en_US
dc.identifier.urihttp://hdl.handle.net/1808/26499
dc.description.abstractCatalytic transformation of CH4 under a mild condition is significant for efficient utilization of shale gas under the circumstance of switching raw materials of chemical industries to shale gas. Here, we report the transformation of CH4 to acetic acid and methanol through coupling of CH4, CO and O2 on single-site Rh1O5 anchored in microporous aluminosilicates in solution at ≤150 °C. The activity of these singly dispersed precious metal sites for production of organic oxygenates can reach about 0.10 acetic acid molecules on a Rh1O5 site per second at 150 °C with a selectivity of ~70% for production of acetic acid. It is higher than the activity of free Rh cations by >1000 times. Computational studies suggest that the first C–H bond of CH4 is activated by Rh1O5 anchored on the wall of micropores of ZSM-5; the formed CH3 then couples with CO and OH, to produce acetic acid over a low activation barrier.en_US
dc.publisherNature Publishing Groupen_US
dc.rightsCopyright © The Author(s) 2018 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.en_US
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/en_US
dc.titleSingle rhodium atoms anchored in micropores for efficient transformation of methane under mild conditionsen_US
dc.typeArticleen_US
kusw.kuauthorTang, Yu
kusw.kuauthorLi, Yuting
kusw.kuauthorHuang, Weixin
kusw.kuauthorZhang, Shiran
kusw.kuauthorNguyen, Luan
kusw.kuauthorZhang, Xiaoyan
kusw.kuauthorTao, Franklin Feng
kusw.kudepartmentChemistryen_US
dc.identifier.doi10.1038/s41467-018-03235-7en_US
kusw.oaversionScholarly/refereed, publisher versionen_US
kusw.oapolicyThis item meets KU Open Access policy criteria.en_US
dc.rights.accessrightsopenAccessen_US


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Copyright © The Author(s) 2018 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
Except where otherwise noted, this item's license is described as: Copyright © The Author(s) 2018 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.