dc.contributor.author | Park, Jonggu | |
dc.contributor.author | Ye, Qiang | |
dc.contributor.author | Singh, Viraj | |
dc.contributor.author | Kieweg, Sarah L. | |
dc.contributor.author | Misra, Anil | |
dc.contributor.author | Spencer, Paulette | |
dc.date.accessioned | 2017-09-01T15:21:49Z | |
dc.date.available | 2017-09-01T15:21:49Z | |
dc.date.issued | 2012-02 | |
dc.identifier.citation | Park, J., Ye, Q., Singh, V., Kieweg, S. L., Misra, A., & Spencer, P. (2012). Synthesis and evaluation of novel dental monomer with branched aromatic carboxylic acid group. Journal of Biomedical Materials Research. Part B, Applied Biomaterials, 100(2), 569–576. http://doi.org/10.1002/jbm.b.31987 | en_US |
dc.identifier.uri | http://hdl.handle.net/1808/24885 | |
dc.description.abstract | A new glycerol-based dimethacrylate monomer with an aromatic carboxylic acid, 2-((1,3-bis(methacryloyloxy)propan-2-yloxy)carbonyl)benzoic acid (BMPB), was synthesized, characterized, and proposed as a possible dental co-monomer for dentin adhesives. Dentin adhesives containing 2-hydroxyethyl methacrylate (HEMA) and 2,2-bis[4-(2-hydroxy-3-methacryloxypropoxy) phenyl]propane (BisGMA) in addition to BMPB were formulated with water at 0, 5, 10, and 15 wt % to simulate wet, oral conditions, and photo-polymerized. Adhesives were characterized with regard to viscosity, real-time photopolymerization behavior, dynamic mechanical analysis, and microscale 3D internal morphologies and compared with HEMA/BisGMA controls. When formulated under wet conditions, the experimental adhesives showed lower viscosities (0.04–0.07 Pa s) as compared to the control (0.09–0.12 Pa s). The experimental adhesives showed higher glass transition temperature (146–157°C), degree of conversion (78–89%), and rubbery moduli (33–36 MPa), and improved water miscibility (no voids) as compared to the controls (123–135°C, 67–71%, 15–26 MPa, and voids, respectively). The enhanced properties of these adhesives suggest that BMPB with simple, straight-forward synthesis is a promising photocurable co-monomer for dental restorative materials. | en_US |
dc.publisher | Wiley | en_US |
dc.rights | This is the peer reviewed version of the following article: Park, J., Ye, Q., Singh, V., Kieweg, S. L., Misra, A., & Spencer, P. (2012). Synthesis and evaluation of novel dental monomer with branched aromatic carboxylic acid group. Journal of Biomedical Materials Research. Part B, Applied Biomaterials, 100(2), 569–576. http://doi.org/10.1002/jbm.b.31987, which has been published in final form at http://doi.org/10.1002/jbm.b.31987. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. | en_US |
dc.subject | Dentin adhesives | en_US |
dc.subject | Dental monomer | en_US |
dc.subject | Photopolymerization | en_US |
dc.subject | Dynamic mechanical property | en_US |
dc.subject | Water miscibility | en_US |
dc.title | Synthesis and evaluation of novel dental monomer with branched aromatic carboxylic acid group | en_US |
dc.type | Article | en_US |
kusw.kuauthor | Park, Jonggu | |
kusw.kuauthor | Ye, Qiang | |
kusw.kuauthor | Singh, Viraj | |
kusw.kuauthor | Kieweg, Sarah L. | |
kusw.kuauthor | Misra, Anil | |
kusw.kuauthor | Spencer, Paulette | |
kusw.kudepartment | Bioengineering Research Center | en_US |
kusw.kudepartment | Mechanical Engineering | en_US |
kusw.kudepartment | Civil, Environmental and Architectural Engineering | en_US |
dc.identifier.doi | 10.1002/jbm.b.31987 | en_US |
kusw.oaversion | Scholarly/refereed, author accepted manuscript | en_US |
kusw.oapolicy | This item meets KU Open Access policy criteria. | en_US |
dc.identifier.pmid | PMC5515472 | en_US |
dc.rights.accessrights | openAccess | |