dc.contributor.author | Park, Jonggu | |
dc.contributor.author | Ye, Qiang | |
dc.contributor.author | Spencer, Paulette | |
dc.contributor.author | Laurence, Jennifer S. | |
dc.date.accessioned | 2017-06-13T20:18:32Z | |
dc.date.available | 2017-06-13T20:18:32Z | |
dc.date.issued | 2012 | |
dc.identifier.citation | Park, J., Ye, Q., Spencer, P., & Laurence, J. S. (2012). Determination of neutralization capacity and stability of a basic methacrylate monomer using NMR. International Journal of Polymeric Materials, 61(2), 144–153. http://doi.org/10.1080/00914037.2011.574660 | en_US |
dc.identifier.uri | http://hdl.handle.net/1808/24495 | |
dc.description | This is an Accepted Manuscript of an article published by Taylor & Francis in International Journal of Polymeric Materials and Polymeric Biomaterials in 2012, available online: http://www.tandfonline.com/10.1080/00914037.2011.574660. | en_US |
dc.description.abstract | The durability of dental resin depends on the stability of the polymer. The neutralizing capacity of a basic methacrylate monomer and its chemical stability were measured using nuclear magnetic resonance (NMR) spectroscopy. Lactic acid solution was titrated with 2-(dimethylamino)ethylmethacrylate (DMAEMA) or 2-hydroxyethylmethacrylate (HEMA) and its chemical shifts monitored. Addition of DMAEMA alters the chemical shift proportionally to pH neutralization, whereas HEMA has no impact. Chemical shifts were used to quantify both the change in pH and monomer stability. The results demonstrate that neutralization by basic monomer can be achieved and that this can be measured using an NMR assay. | en_US |
dc.publisher | Taylor & Francis | en_US |
dc.subject | Neutralization | en_US |
dc.subject | Stability | en_US |
dc.subject | Basic monomer | en_US |
dc.subject | Lactic acid | en_US |
dc.subject | Nuclear magnetic resonance spectroscopy | en_US |
dc.title | Determination of neutralization capacity and stability of a basic methacrylate monomer using NMR | en_US |
dc.type | Article | en_US |
kusw.kuauthor | Park, Jonggu | |
kusw.kuauthor | Ye, Qiang | |
kusw.kuauthor | Spencer, Paulette | |
kusw.kuauthor | Laurence, Jennifer S. | |
kusw.kudepartment | Bioengineering | en_US |
kusw.oanotes | Per SHERPA/RoMEO 6/13/2017: Author's Pre-print: green tick author can archive pre-print (ie pre-refereeing)
Author's Post-print: green tick author can archive post-print (ie final draft post-refereeing)
Publisher's Version/PDF: cross author cannot archive publisher's version/PDF
General Conditions: Some individual journals may have policies prohibiting pre-print archiving
On author's personal website or departmental website immediately
On institutional repository, subject-based repository or academic social network (Mendeley, ResearchGate or Academia.edu) after 12 months embargo
Publisher's version/PDF cannot be used
On a non-profit server
Published source must be acknowledged
Must link to publisher version
Set statements to accompany deposits (see policy)
The publisher will deposit in on behalf of authors to a designated institutional repository including PubMed Central, where a deposit agreement exists with the repository | en_US |
dc.identifier.doi | 10.1080/00914037.2011.574660 | en_US |
kusw.oaversion | Scholarly/refereed, author accepted manuscript | en_US |
kusw.oapolicy | This item meets KU Open Access policy criteria. | en_US |
dc.identifier.pmid | PMC3337788 | en_US |
dc.rights.accessrights | openAccess | |