dc.contributor.author | Lang, Simon Bouyea | |
dc.contributor.author | O'Nele, Kathryn M. | |
dc.contributor.author | Douglas, Justin T. | |
dc.contributor.author | Tunge, Jon A. | |
dc.date.accessioned | 2017-06-01T16:22:48Z | |
dc.date.available | 2017-06-01T16:22:48Z | |
dc.date.issued | 2015-12-14 | |
dc.identifier.citation | Lang, S. B., O'Nele, K. M., Douglas, J. T. and Tunge, J. A. (2015), Dual Catalytic Decarboxylative Allylations of α-Amino Acids and Their Divergent Mechanisms. Chem. Eur. J., 21: 18589–18593. doi:10.1002/chem.201503644 | en_US |
dc.identifier.uri | http://hdl.handle.net/1808/24331 | |
dc.description | This is the peer reviewed version of the following article: Lang, S. B., O'Nele, K. M., Douglas, J. T. and Tunge, J. A. (2015), Dual Catalytic Decarboxylative Allylations of α-Amino Acids and Their Divergent Mechanisms. Chem. Eur. J., 21: 18589–18593. doi:10.1002/chem.201503644, which has been published in final form at http://doi.org/10.1002/chem.201503644. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. | en_US |
dc.description.abstract | The room temperature radical decarboxylative allylation of N-protected α-amino acids and esters has been accomplished via a combination of palladium and photoredox catalysis to provide homoallylic amines. Mechanistic investigations revealed that the stability of the α-amino radical, which is formed by decarboxylation, dictates the predominant reaction pathway between competing mechanisms. | en_US |
dc.publisher | Wiley | en_US |
dc.title | Dual catalytic decarboxylative allylations of α-amino acids and their divergent mechanisms | en_US |
dc.type | Article | en_US |
kusw.kuauthor | Lang, Simon B. | |
kusw.kuauthor | O'Nele, Kathryn M. | |
kusw.kuauthor | Douglas, Justin T. | |
kusw.kuauthor | Tunge, Jon A. | |
kusw.kudepartment | Chemistry | en_US |
dc.identifier.doi | 10.1002/chem.201503644 | en_US |
kusw.oaversion | Scholarly/refereed, author accepted manuscript | en_US |
kusw.oapolicy | This item meets KU Open Access policy criteria. | en_US |
dc.identifier.pmid | PMC4715668 | en_US |
dc.rights.accessrights | openAccess | |