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dc.contributor.authorLang, Simon Bouyea
dc.contributor.authorO'Nele, Kathryn M.
dc.contributor.authorDouglas, Justin T.
dc.contributor.authorTunge, Jon A.
dc.date.accessioned2017-06-01T16:22:48Z
dc.date.available2017-06-01T16:22:48Z
dc.date.issued2015-12-14
dc.identifier.citationLang, S. B., O'Nele, K. M., Douglas, J. T. and Tunge, J. A. (2015), Dual Catalytic Decarboxylative Allylations of α-Amino Acids and Their Divergent Mechanisms. Chem. Eur. J., 21: 18589–18593. doi:10.1002/chem.201503644en_US
dc.identifier.urihttp://hdl.handle.net/1808/24331
dc.descriptionThis is the peer reviewed version of the following article: Lang, S. B., O'Nele, K. M., Douglas, J. T. and Tunge, J. A. (2015), Dual Catalytic Decarboxylative Allylations of α-Amino Acids and Their Divergent Mechanisms. Chem. Eur. J., 21: 18589–18593. doi:10.1002/chem.201503644, which has been published in final form at http://doi.org/10.1002/chem.201503644. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.en_US
dc.description.abstractThe room temperature radical decarboxylative allylation of N-protected α-amino acids and esters has been accomplished via a combination of palladium and photoredox catalysis to provide homoallylic amines. Mechanistic investigations revealed that the stability of the α-amino radical, which is formed by decarboxylation, dictates the predominant reaction pathway between competing mechanisms.en_US
dc.publisherWileyen_US
dc.titleDual catalytic decarboxylative allylations of α-amino acids and their divergent mechanismsen_US
dc.typeArticleen_US
kusw.kuauthorLang, Simon B.
kusw.kuauthorO'Nele, Kathryn M.
kusw.kuauthorDouglas, Justin T.
kusw.kuauthorTunge, Jon A.
kusw.kudepartmentChemistryen_US
dc.identifier.doi10.1002/chem.201503644en_US
kusw.oaversionScholarly/refereed, author accepted manuscripten_US
kusw.oapolicyThis item meets KU Open Access policy criteria.en_US
dc.identifier.pmidPMC4715668en_US
dc.rights.accessrightsopenAccess


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