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Synthesis of 1,5-Dioxocanes via the Two-Fold C-O Bond Forming Nucleophilic 4+4-Cyclodimerization of Cycloprop-2-en-1-ylmethanols
dc.contributor.author | Edwards, Andrew | |
dc.contributor.author | Bennin, Trevor | |
dc.contributor.author | Rubina, Marina | |
dc.contributor.author | Rubin, Michael | |
dc.date.accessioned | 2017-05-31T15:29:30Z | |
dc.date.available | 2017-05-31T15:29:30Z | |
dc.date.issued | 2015-08-19 | |
dc.identifier.citation | Edwards, A., Bennin, T., Rubina, M., & Rubin, M. (2015). Synthesis of 1,5-Dioxocanes via the Two-Fold C-O Bond Forming Nucleophilic 4+4-Cyclodimerization of Cycloprop-2-en-1-ylmethanols. RSC Advances, 5(88), 71849–71853. http://doi.org/10.1039/C5RA14077C | en_US |
dc.identifier.uri | http://hdl.handle.net/1808/24314 | |
dc.description.abstract | An efficient [4+4] cyclodimerization of cyclopropenemethanols operating via a two-fold strain release-driven addition of alkoxides across the double bond of cyclopropenes was investigated. This chemo- and diastereoselective transformation provided previously unknown 2,7-dioxatricyclo[7.1.0.04,6]decane scaffolds. | en_US |
dc.publisher | Royal Society of Chemistry | en_US |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | en_US |
dc.title | Synthesis of 1,5-Dioxocanes via the Two-Fold C-O Bond Forming Nucleophilic 4+4-Cyclodimerization of Cycloprop-2-en-1-ylmethanols | en_US |
dc.type | Article | en_US |
kusw.kuauthor | Edwards, Andrew | |
kusw.kuauthor | Bennin, Trevor | |
kusw.kuauthor | Rubina, Marina | |
kusw.kuauthor | Rubin, Michael | |
kusw.kudepartment | Chemistry | en_US |
dc.identifier.doi | 10.1039/c5ra14077c | en_US |
dc.identifier.orcid | https://orcid.org/0000-0002-1668-9311 | |
dcterms.rights | This is an open access article under the terms of the Creative Commons Attribution-NonCommercial-NoDerivs License 4.0 (CC BY-NC-ND 4.0), which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made. | |
kusw.oaversion | Scholarly/refereed, publisher version | en_US |
kusw.oapolicy | This item meets KU Open Access policy criteria. | en_US |
dc.identifier.pmid | PMC4652585 | en_US |
dc.rights.accessrights | openAccess |