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Silica-Supported Oligomeric Benzyl Phosphate (Si-OBP) and Triazole Phosphate (Si-OTP) Alkylating Reagents
| dc.contributor.author | Maity, Pradip K. | |
| dc.contributor.author | Faisal, Saqib | |
| dc.contributor.author | Rolfe, Alan | |
| dc.contributor.author | Stoianova, Diana | |
| dc.contributor.author | Hanson, Paul R. | |
| dc.date.accessioned | 2017-04-12T18:31:38Z | |
| dc.date.available | 2017-04-12T18:31:38Z | |
| dc.date.issued | 2015-10-16 | |
| dc.identifier.citation | Maity, P. K., Faisal, S., Rolfe, A., Stoianova, D., & Hanson, P. R. (2015). Silica-Supported Oligomeric Benzyl Phosphate (Si-OBP) and Triazole Phosphate (Si-OTP) Alkylating Reagents. The Journal of Organic Chemistry, 80(20), 9942–9950. http://doi.org/10.1021/acs.joc.5b01456 | en_US |
| dc.identifier.uri | http://hdl.handle.net/1808/23643 | |
| dc.description.abstract | The syntheses of silica-supported oligomeric benzyl phosphates (Si-OBPn) and triazole phosphates (Si-OTPn) using ring-opening metathesis polymerization (ROMP) for use as efficient alkylating reagents is reported. Ease of synthesis and grafting onto the surface of norbornenyl-tagged (Nb-tagged) silica particles has been demonstrated for benzyl phosphate and triazole phosphate monomers. It is shown that these silica polymer hybrid reagents, Si-OBPn and Si-OTPn, can be used to carry out alkylation reactions with an array of different nucleophiles to afford the corresponding benzylated and (triazolyl)methylated products in good yield and high purity. | en_US |
| dc.publisher | American Chemical Society | en_US |
| dc.rights | This document is the Accepted Manuscript version of a Published Work that appeared in final form in the Journal of Organic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/acs.joc.5b01456. | en_US |
| dc.title | Silica-Supported Oligomeric Benzyl Phosphate (Si-OBP) and Triazole Phosphate (Si-OTP) Alkylating Reagents | en_US |
| dc.type | Article | en_US |
| kusw.kuauthor | Maity, Pradip K. | |
| kusw.kuauthor | Faisal, Saqib | |
| kusw.kuauthor | Rolfe, Alan | |
| kusw.kuauthor | Stoianova, Diana | |
| kusw.kuauthor | Hanson, Paul R. | |
| kusw.kudepartment | Chemistry | en_US |
| dc.identifier.doi | 10.1021/acs.joc.5b01456 | en_US |
| kusw.oaversion | Scholarly/refereed, author accepted manuscript | en_US |
| kusw.oapolicy | This item meets KU Open Access policy criteria. | en_US |
| dc.rights.accessrights | openAccess |
