Silica-Supported Oligomeric Benzyl Phosphate (Si-OBP) and Triazole Phosphate (Si-OTP) Alkylating Reagents

Maity, Pradip K.; Faisal, Saqib; Rolfe, Alan; Stoianova, Diana; Hanson, Paul R.

dc.contributor.author	Maity, Pradip K.
dc.contributor.author	Faisal, Saqib
dc.contributor.author	Rolfe, Alan
dc.contributor.author	Stoianova, Diana
dc.contributor.author	Hanson, Paul R.
dc.date.accessioned	2017-04-12T18:31:38Z
dc.date.available	2017-04-12T18:31:38Z
dc.date.issued	2015-10-16
dc.identifier.citation	Maity, P. K., Faisal, S., Rolfe, A., Stoianova, D., & Hanson, P. R. (2015). Silica-Supported Oligomeric Benzyl Phosphate (Si-OBP) and Triazole Phosphate (Si-OTP) Alkylating Reagents. The Journal of Organic Chemistry, 80(20), 9942–9950. http://doi.org/10.1021/acs.joc.5b01456	en_US
dc.identifier.uri	http://hdl.handle.net/1808/23643
dc.description.abstract	The syntheses of silica-supported oligomeric benzyl phosphates (Si-OBPn) and triazole phosphates (Si-OTPn) using ring-opening metathesis polymerization (ROMP) for use as efficient alkylating reagents is reported. Ease of synthesis and grafting onto the surface of norbornenyl-tagged (Nb-tagged) silica particles has been demonstrated for benzyl phosphate and triazole phosphate monomers. It is shown that these silica polymer hybrid reagents, Si-OBPn and Si-OTPn, can be used to carry out alkylation reactions with an array of different nucleophiles to afford the corresponding benzylated and (triazolyl)methylated products in good yield and high purity.	en_US
dc.publisher	American Chemical Society	en_US
dc.rights	This document is the Accepted Manuscript version of a Published Work that appeared in final form in the Journal of Organic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/acs.joc.5b01456.	en_US
dc.title	Silica-Supported Oligomeric Benzyl Phosphate (Si-OBP) and Triazole Phosphate (Si-OTP) Alkylating Reagents	en_US
dc.type	Article	en_US
kusw.kuauthor	Maity, Pradip K.
kusw.kuauthor	Faisal, Saqib
kusw.kuauthor	Rolfe, Alan
kusw.kuauthor	Stoianova, Diana
kusw.kuauthor	Hanson, Paul R.
kusw.kudepartment	Chemistry	en_US
dc.identifier.doi	10.1021/acs.joc.5b01456	en_US
kusw.oaversion	Scholarly/refereed, author accepted manuscript	en_US
kusw.oapolicy	This item meets KU Open Access policy criteria.	en_US
dc.rights.accessrights	openAccess

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