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    Lewis acid-catalyzed diastereoselective hydroarylation of benzylidene malonic esters

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    TungeJ_2009.pdf (290.6Kb)
    Issue Date
    2009-06-19
    Author
    Duan, Shaofeng
    Jana, Ranjan
    Tunge, Jon A.
    Publisher
    American Chemical Society
    Type
    Article
    Article Version
    Scholarly/refereed, author accepted manuscript
    Rights
    This document is the Accepted Manuscript version of a Published Work that appeared in final form in the Journal of Organic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/jo900367g.
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    Abstract
    Herein we report that simple Lewis acids catalyze the hydroarylation of benzylidene malonates with phenols. Ultimately, 3,4-disubstituted dihydrocoumarins are obtained via a hydroarylation-lactonization sequence. Moreover, the dihydrocoumarins are formed with a high degree of diastereoselectivity favoring the trans stereoisomer.
    URI
    http://hdl.handle.net/1808/23640
    DOI
    https://doi.org/10.1021/jo900367g
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    • Chemistry Scholarly Works [610]
    Citation
    Duan, S., Jana, R., & Tunge, J. A. (2009). Lewis acid-catalyzed diastereoselective hydroarylation of benzylidene malonic esters. The Journal of Organic Chemistry, 74(12), 4612–4614. http://doi.org/10.1021/jo900367g

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    Contact KU ScholarWorks
    785-864-8983
    KU Libraries
    1425 Jayhawk Blvd
    Lawrence, KS 66045
    785-864-8983

    KU Libraries
    1425 Jayhawk Blvd
    Lawrence, KS 66045
    Image Credits
     

     

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