ATTENTION: The software behind KU ScholarWorks is being upgraded to a new version. Starting July 15th, users will not be able to log in to the system, add items, nor make any changes until the new version is in place at the end of July. Searching for articles and opening files will continue to work while the system is being updated.
If you have any questions, please contact Marianne Reed at mreed@ku.edu .
The Power of Solvent in Altering the Course of Photorearrangements
| dc.contributor.author | Šebej, Peter | |
| dc.contributor.author | Lim, Bum Hee | |
| dc.contributor.author | Park, Bong Ser | |
| dc.contributor.author | Givens, Richard S. | |
| dc.contributor.author | Klán, Petr | |
| dc.date.accessioned | 2017-03-28T18:14:27Z | |
| dc.date.available | 2017-03-28T18:14:27Z | |
| dc.date.issued | 2011-02-18 | |
| dc.identifier.citation | Šebej, P., Lim, B. H., Park, B. S., Givens, R. S., & Klán, P. (2011). The Power of Solvent in Altering the Course of Photorearrangements. Organic Letters, 13(4), 644–647. http://doi.org/10.1021/ol102887f | en_US |
| dc.identifier.uri | http://hdl.handle.net/1808/23501 | |
| dc.description.abstract | A clean bifurcation between two important photochemical reactions through competition of a triplet state Type II H-abstraction reaction with a photo-Favorskii rearrangement for (o/p)-hydroxy-o-methylphenacyl esters that depends on the water content of the solvent has been established. The switch from the anhydrous Type II pathway that yields indanones to the aqueous-dependent pathway producing benzofuranones occurs abruptly at low water concentrations (~8%). The surprisingly clean yields suggest that such reactions are synthetically promising. | en_US |
| dc.publisher | American Chemical Society | en_US |
| dc.rights | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/ol102887f. | en_US |
| dc.title | The Power of Solvent in Altering the Course of Photorearrangements | en_US |
| dc.type | Article | en_US |
| kusw.kuauthor | Šebej, Peter | |
| kusw.kuauthor | Givens, Richard S. | |
| kusw.kudepartment | Chemistry | en_US |
| dc.identifier.doi | 10.1021/ol102887f | en_US |
| kusw.oaversion | Scholarly/refereed, author accepted manuscript | en_US |
| kusw.oapolicy | This item meets KU Open Access policy criteria. | en_US |
| dc.rights.accessrights | openAccess |
