ROMP-derived Oligomeric Phosphates for Application in Facile Benzylation

Long, Toby R.; Maity, Pradip K.; Samarakoon, Thiwanka Bandara; Hanson, Paul R.

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Issue Date

2010-07-12

Author

Long, Toby R.

Maity, Pradip K.

Samarakoon, Thiwanka Bandara

Hanson, Paul R.

Publisher

American Chemical Society

Type

Article

Article Version

Scholarly/refereed, author accepted manuscript

Rights

This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/ol1006604.

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Abstract

The development of new ROMP-based oligomeric benzyl phosphates (OBPn) is reported for use as soluble, stable benzylating reagents. These oligomeric reagents are readily synthesized from commercially available materials and conveniently polymerized and purified in a one-pot process, affording bench stable, pure white, free-flowing solids on multi-gram scale. Utilization in benzylation reactions with a variety of nucleophiles is reported.

Citation

Long, T. R., Maity, P. K., Samarakoon, T. B., & Hanson, P. R. (2010). ROMP-derived Oligomeric Phosphates for Application in Facile Benzylation. Organic Letters, 12(13), 2904–2907. http://doi.org/10.1021/ol1006604

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