dc.contributor.author | Grenning, Alexander J. | |
dc.contributor.author | Tunge, Jon A. | |
dc.date.accessioned | 2017-03-24T17:49:21Z | |
dc.date.available | 2017-03-24T17:49:21Z | |
dc.date.issued | 2010-02-19 | |
dc.identifier.citation | Grenning, A. J., & Tunge, J. A. (2010). Rapid decarboxylative allylation of nitroalkanes. Organic Letters, 12(4), 740. http://doi.org/10.1021/ol902828p | en_US |
dc.identifier.uri | http://hdl.handle.net/1808/23485 | |
dc.description.abstract | Allyl nitroacetates undergo decarboxylative allylation to provide tertiary nitroalkanes in high yield. Moreover, the transformations are complete within several minutes under ambient conditions. High yields result because O-allylation of the intermediate nitronates, which is typically problematic, is reversible under conditions of the decarboxylative allylation process. Lastly, the preparation of substrate allyl nitroacetates by tandem Knoevenagel/Diels-Alder sequences allows the facile synthesis of relatively complex substrates that undergo diastereoselective decarboxylative allylation. | en_US |
dc.publisher | American Chemical Society | en_US |
dc.title | Rapid decarboxylative allylation of nitroalkanes | en_US |
dc.type | Article | en_US |
kusw.kuauthor | Grenning, Alexander J. | |
kusw.kuauthor | Tunge, Jon A. | |
kusw.kudepartment | Chemistry | en_US |
dc.identifier.doi | 10.1021/ol902828p | en_US |
kusw.oaversion | Scholarly/refereed, author accepted manuscript | en_US |
kusw.oapolicy | This item meets KU Open Access policy criteria. | en_US |
dc.rights.accessrights | openAccess | |