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Palladium-catalyzed Transformations of Salvinorin A, a Neoclerodane Diterpene from Salvia divinorum
dc.contributor.author | Riley, Andrew Philip | |
dc.contributor.author | Day, Victor W. | |
dc.contributor.author | Navarro, Hernán A. | |
dc.contributor.author | Prisinzano, Thomas E. | |
dc.date.accessioned | 2017-03-24T17:32:58Z | |
dc.date.available | 2017-03-24T17:32:58Z | |
dc.date.issued | 2013-12-06 | |
dc.identifier.citation | Riley, A. P., Day, V. W., Navarro, H. A., & Prisinzano, T. E. (2013). Palladium-catalyzed Transformations of Salvinorin A, a Neoclerodane Diterpene from Salvia divinorum. Organic Letters, 15(23), 5936–5939. http://doi.org/10.1021/ol4027528 | en_US |
dc.identifier.uri | http://hdl.handle.net/1808/23484 | |
dc.description.abstract | Transformations that selectively modify the furan ring present in a variety of naturals products would be useful in the synthesis of biological probes but remain largely underexplored. The neoclerodane diterpene salvinorin A, isolated from Salvia divinorum, is an example of a furan-containing natural product. Following selective bromination of salvinorin A, Suzuki-Miyaura and Sonogashira couplings were accomplished in moderate to good yields without hydrolyzing the labile C-2 acetate or altering the stereochemistry of the epimerizable centers. | en_US |
dc.publisher | American Chemical Society | en_US |
dc.rights | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://doi.org/10.1021/ol4027528. | |
dc.title | Palladium-catalyzed Transformations of Salvinorin A, a Neoclerodane Diterpene from Salvia divinorum | en_US |
dc.type | Article | en_US |
kusw.kuauthor | Riley, Andrew P. | |
kusw.kuauthor | Day, Victor W. | |
kusw.kuauthor | Prisinzano, Thomas E. | |
kusw.kudepartment | Chemistry | en_US |
dc.identifier.doi | 10.1021/ol4027528 | en_US |
kusw.oaversion | Scholarly/refereed, author accepted manuscript | en_US |
kusw.oapolicy | This item meets KU Open Access policy criteria. | en_US |
dc.rights.accessrights | openAccess |