ATTENTION: The software behind KU ScholarWorks is being upgraded to a new version. Starting July 15th, users will not be able to log in to the system, add items, nor make any changes until the new version is in place at the end of July. Searching for articles and opening files will continue to work while the system is being updated. If you have any questions, please contact Marianne Reed at mreed@ku.edu .

Show simple item record

dc.contributor.authorRiley, Andrew Philip
dc.contributor.authorDay, Victor W.
dc.contributor.authorNavarro, Hernán A.
dc.contributor.authorPrisinzano, Thomas E.
dc.date.accessioned2017-03-24T17:32:58Z
dc.date.available2017-03-24T17:32:58Z
dc.date.issued2013-12-06
dc.identifier.citationRiley, A. P., Day, V. W., Navarro, H. A., & Prisinzano, T. E. (2013). Palladium-catalyzed Transformations of Salvinorin A, a Neoclerodane Diterpene from Salvia divinorum. Organic Letters, 15(23), 5936–5939. http://doi.org/10.1021/ol4027528en_US
dc.identifier.urihttp://hdl.handle.net/1808/23484
dc.description.abstractTransformations that selectively modify the furan ring present in a variety of naturals products would be useful in the synthesis of biological probes but remain largely underexplored. The neoclerodane diterpene salvinorin A, isolated from Salvia divinorum, is an example of a furan-containing natural product. Following selective bromination of salvinorin A, Suzuki-Miyaura and Sonogashira couplings were accomplished in moderate to good yields without hydrolyzing the labile C-2 acetate or altering the stereochemistry of the epimerizable centers.en_US
dc.publisherAmerican Chemical Societyen_US
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://doi.org/10.1021/ol4027528.
dc.titlePalladium-catalyzed Transformations of Salvinorin A, a Neoclerodane Diterpene from Salvia divinorumen_US
dc.typeArticleen_US
kusw.kuauthorRiley, Andrew P.
kusw.kuauthorDay, Victor W.
kusw.kuauthorPrisinzano, Thomas E.
kusw.kudepartmentChemistryen_US
dc.identifier.doi10.1021/ol4027528en_US
kusw.oaversionScholarly/refereed, author accepted manuscripten_US
kusw.oapolicyThis item meets KU Open Access policy criteria.en_US
dc.rights.accessrightsopenAccess


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record