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Mild Decarboxylative Allylation of Coumarins
| dc.contributor.author | Jana, Ranjan | |
| dc.contributor.author | Trivedi, Rushi | |
| dc.contributor.author | Tunge, Jon A. | |
| dc.date.accessioned | 2017-03-23T17:13:14Z | |
| dc.date.available | 2017-03-23T17:13:14Z | |
| dc.date.issued | 2009-08-06 | |
| dc.identifier.citation | Jana, R., Trivedi, R., & Tunge, J. A. (2009). Mild Decarboxylative Allylation of Coumarins. Organic Letters, 11(15), 3434–3436. http://doi.org/10.1021/ol901288r | en_US |
| dc.identifier.uri | http://hdl.handle.net/1808/23476 | |
| dc.description.abstract | Allyl esters of 3-carboxylcoumarins undergo facile decarboxylative coupling at just 25–50 °C. This represents the first extension of decarboxylative C–C bond-forming reactions to the coupling of aromatics with sp3-hybridized electrophiles. Finally, the same concept can be applied to the sp2–sp3 couplings of pyrones and flavones. Thus, a variety of biologically important heteroaromatics can be readily functionalized without the need for strong bases or stoichiometric organometallics that are typically required for more standard cross-coupling reactions. | en_US |
| dc.publisher | American Chemical Society | en_US |
| dc.rights | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/ol901288r. | en_US |
| dc.title | Mild Decarboxylative Allylation of Coumarins | en_US |
| dc.type | Article | en_US |
| kusw.kuauthor | Jana, Ranjan | |
| kusw.kuauthor | Trivedi, Rushi | |
| kusw.kuauthor | Tunge, Jon A. | |
| kusw.kudepartment | Chemistry | en_US |
| dc.identifier.doi | 10.1021/ol901288 | en_US |
| kusw.oaversion | Scholarly/refereed, author accepted manuscript | en_US |
| kusw.oapolicy | This item meets KU Open Access policy criteria. | en_US |
| dc.rights.accessrights | openAccess |
