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dc.contributor.authorChattopadhyay, Kalicharan
dc.contributor.authorJana, Ranjan
dc.contributor.authorDay, Victor W.
dc.contributor.authorDouglas, Justin T.
dc.contributor.authorTunge, Jon A.
dc.identifier.citationChattopadhyay, K., Jana, R., Day, V. W., Douglas, J. T., & Tunge, J. A. (2010). Mechanistic origin of the stereodivergence in decarboxylative allylation. Organic Letters, 12(13), 3042–3045.
dc.description.abstractA stereochemical test has been used to probe the mechanism of decarboxylative allylation. This probe suggests that the mechanism of DcA reactions can change based on the substitution pattern at the α-carbon of the nucleophile, however reaction via stabilized malonate nucleophiles is the lower energy pathway. Lastly, this mechanistic proposal has predictive power and can be used to explain chemoselectivities in decarboxylative reactions that were previously confounding.en_US
dc.publisherAmerican Chemical Societyen_US
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see
dc.titleMechanistic origin of the stereodivergence in decarboxylative allylationen_US
kusw.kuauthorChattopadhyay, Kalicharan
kusw.kuauthorJana, Ranjan
kusw.kuauthorDay, Victor W.
kusw.kuauthorDouglas, Justin T.
kusw.kuauthorTunge, Jon A.
kusw.oaversionScholarly/refereed, author accepted manuscripten_US
kusw.oapolicyThis item meets KU Open Access policy criteria.en_US

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