| dc.contributor.author | Chattopadhyay, Kalicharan | |
| dc.contributor.author | Jana, Ranjan | |
| dc.contributor.author | Day, Victor W. | |
| dc.contributor.author | Douglas, Justin T. | |
| dc.contributor.author | Tunge, Jon A. | |
| dc.date.accessioned | 2017-03-23T16:59:29Z | |
| dc.date.available | 2017-03-23T16:59:29Z | |
| dc.date.issued | 2010-07-02 | |
| dc.identifier.citation | Chattopadhyay, K., Jana, R., Day, V. W., Douglas, J. T., & Tunge, J. A. (2010). Mechanistic origin of the stereodivergence in decarboxylative allylation. Organic Letters, 12(13), 3042–3045. http://doi.org/10.1021/ol101042x | en_US |
| dc.identifier.uri | http://hdl.handle.net/1808/23475 | |
| dc.description.abstract | A stereochemical test has been used to probe the mechanism of decarboxylative allylation. This probe suggests that the mechanism of DcA reactions can change based on the substitution pattern at the α-carbon of the nucleophile, however reaction via stabilized malonate nucleophiles is the lower energy pathway. Lastly, this mechanistic proposal has predictive power and can be used to explain chemoselectivities in decarboxylative reactions that were previously confounding. | en_US |
| dc.publisher | American Chemical Society | en_US |
| dc.rights | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/ol101042x. | en_US |
| dc.title | Mechanistic origin of the stereodivergence in decarboxylative allylation | en_US |
| dc.type | Article | en_US |
| kusw.kuauthor | Chattopadhyay, Kalicharan | |
| kusw.kuauthor | Jana, Ranjan | |
| kusw.kuauthor | Day, Victor W. | |
| kusw.kuauthor | Douglas, Justin T. | |
| kusw.kuauthor | Tunge, Jon A. | |
| kusw.kudepartment | Chemistry | en_US |
| dc.identifier.doi | 10.1021/ol101042x | en_US |
| kusw.oaversion | Scholarly/refereed, author accepted manuscript | en_US |
| kusw.oapolicy | This item meets KU Open Access policy criteria. | en_US |
| dc.rights.accessrights | openAccess | |
