High-Load, Hybrid Si-ROMP Reagents

Rolfe, Alan; Loh, Joanna K.; Maity, Pradip K.; Hanson, Paul R.

dc.contributor.author	Rolfe, Alan
dc.contributor.author	Loh, Joanna K.
dc.contributor.author	Maity, Pradip K.
dc.contributor.author	Hanson, Paul R.
dc.date.accessioned	2017-03-23T16:27:26Z
dc.date.available	2017-03-23T16:27:26Z
dc.date.issued	2011-01-07
dc.identifier.citation	Rolfe, A., Loh, J. K., Maity, P. K., & Hanson, P. R. (2011). High-Load, Hybrid Si-ROMP Reagents. Organic Letters, 13(1), 4–7. http://doi.org/10.1021/ol102239h	en_US
dc.identifier.uri	http://hdl.handle.net/1808/23473
dc.description.abstract	The combination of norbornenyl-tagged (Nb-tagged) silica particles and functionalized Nb-tagged monomers for the generation of hybrid Si-ROMP reagents and scavengers is reported. Specifically Si-ROMP-derived bis-acid chloride, dichlorotriazine and triphenylphosphine scavenger/reagents have been grafted from the surface of silica particles utilizating surface-initiated, ring-opening metathesis polymerization (ROMP). These hybridpolymeric materials combine the physical properties of current immobilized silica reagents and represent a key advancement in load by merging the inherent tunable properties of the ROMP-derived oligomers with silica supports for application in parallel synthesis.	en_US
dc.publisher	American Chemical Society	en_US
dc.rights	This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/ol102239h	en_US
dc.title	High-Load, Hybrid Si-ROMP Reagents	en_US
dc.type	Article	en_US
kusw.kuauthor	Rolfe, Alan
kusw.kuauthor	Loh, Joanna K.
kusw.kuauthor	Maity, Pradip K.
kusw.kuauthor	Hanson, Paul R.
kusw.kudepartment	Chemistry	en_US
dc.identifier.doi	10.1021/ol102239h	en_US
kusw.oaversion	Scholarly/refereed, author accepted manuscript	en_US
kusw.oapolicy	This item meets KU Open Access policy criteria.	en_US
dc.rights.accessrights	openAccess

Files in this item

Name:: Rolfe_2011.pdf
Size:: 1.638Mb
Format:: PDF

View/Open

This item appears in the following Collection(s)

The University of Kansas prohibits discrimination on the basis of race, color, ethnicity, religion, sex, national origin, age, ancestry, disability, status as a veteran, sexual orientation, marital status, parental status, gender identity, gender expression and genetic information in the University’s programs and activities. The following person has been designated to handle inquiries regarding the non-discrimination policies: Director of the Office of Institutional Opportunity and Access, IOA@ku.edu, 1246 W. Campus Road, Room 153A, Lawrence, KS, 66045, (785)864-6414, 711 TTY.