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    Metal-free transannulation reaction of indoles with nitrostyrenes: a simple practical synthesis of 3-substituted 2-quinolones

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    Issue Date
    2016-07-15
    Author
    Aksenov, Alexander V.
    Smirnov, Alexander N.
    Aksenov, Nicolai A.
    Aksenova, Inna V.
    Frolova, Liliya V.
    Kornienko, Alexander
    Magedov, Igor V.
    Rubin, Michael
    Publisher
    Royal Society of Chemistry
    Type
    Article
    Article Version
    Scholarly/refereed, author accepted manuscript
    Metadata
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    Abstract
    3-Substituted 2-quinolones are obtained via a novel, metal-free transannulation reaction of 2-substituted indoles with 2-nitroalkenes in polyphosphoric acid. The reaction can be used in conjunction with the Fisher indole synthesis offering a practical three-component heteroannulation methodology to produce 2-quinolones from arylhydrazines, 2-nitroalkenes and acetophenone.
    URI
    http://hdl.handle.net/1808/23223
    DOI
    https://doi.org/10.1039/c3cc45696j
    Collections
    • Chemistry Scholarly Works [616]
    Citation
    Aksenov, Alexander V., Alexander N. Smirnov, Nicolai A. Aksenov, Inna V. Aksenova, Liliya V. Frolova, Alexander Kornienko, Igor V. Magedov, and Michael Rubin. "Metal-free Transannulation Reaction of Indoles with Nitrostyrenes: A Simple Practical Synthesis of 3-substituted 2-quinolones." Chemical Communications 49.81 (2013): 9305.

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    Contact KU ScholarWorks
    785-864-8983
    KU Libraries
    1425 Jayhawk Blvd
    Lawrence, KS 66045
    785-864-8983

    KU Libraries
    1425 Jayhawk Blvd
    Lawrence, KS 66045
    Image Credits
     

     

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