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    Catalytic Intermolecular Hydroamination of Vinyl Ethers

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    Issue Date
    2009-07-30
    Author
    Pahadi, Nirmal K.
    Tunge, Jon A.
    Publisher
    Thieme Publishing
    Type
    Article
    Article Version
    Scholarly/refereed, publisher version
    Published Version
    https://www.thieme-connect.de/products/ejournals/html/10.1055/s-0029-1218293
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    Abstract
    This manuscript details the development of a palladium-catalyzed hydroamination of vinyl ethers. It is proposed that palladium catalyzes the hydroamination via Brønsted base catalysis, where palladium is protonated by the relatively acidic sulfonamide to generate a palladium hydride as well as the active anionic sulfonamide nucleophile. Thus, this process is distinct from known palladium-catalyzed hydroaminations of styrene derivatives that utilize less acidic amines.
    URI
    http://hdl.handle.net/1808/22457
    DOI
    https://doi.org/10.1055/s-0029-1218293
    Collections
    • Chemistry Scholarly Works [601]
    Citation
    Pahadi, Nirmal, and Jon Tunge. "Catalytic Intermolecular Hydroamination of Vinyl Ethers." Synlett 2009.19 (2009): 3135-138.

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    Contact KU ScholarWorks
    785-864-8983
    KU Libraries
    1425 Jayhawk Blvd
    Lawrence, KS 66045
    785-864-8983

    KU Libraries
    1425 Jayhawk Blvd
    Lawrence, KS 66045
    Image Credits
     

     

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