Catalytic Intermolecular Hydroamination of Vinyl Ethers

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Issue Date
2009-07-30Author
Pahadi, Nirmal K.
Tunge, Jon A.
Publisher
Thieme Publishing
Type
Article
Article Version
Scholarly/refereed, publisher version
Metadata
Show full item recordAbstract
This manuscript details the development of a palladium-catalyzed hydroamination of vinyl ethers. It is proposed that palladium catalyzes the hydroamination via Brønsted base catalysis, where palladium is protonated by the relatively acidic sulfonamide to generate a palladium hydride as well as the active anionic sulfonamide nucleophile. Thus, this process is distinct from known palladium-catalyzed hydroaminations of styrene derivatives that utilize less acidic amines.
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Citation
Pahadi, Nirmal, and Jon Tunge. "Catalytic Intermolecular Hydroamination of Vinyl Ethers." Synlett 2009.19 (2009): 3135-138.
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