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Anodic deposition of a robust iridium-based water-oxidation catalyst from organometallic precursors
dc.contributor.author | Blakemore, James D. | |
dc.contributor.author | Schley, Nathan D. | |
dc.contributor.author | Olack, Gerard W. | |
dc.contributor.author | Incarvito, Christopher D. | |
dc.contributor.author | Brudvig, Gary W. | |
dc.contributor.author | Crabtree, Robert H. | |
dc.date.accessioned | 2016-07-28T17:37:38Z | |
dc.date.available | 2016-07-28T17:37:38Z | |
dc.date.issued | 2011 | |
dc.identifier.citation | Blakemore, J. D., Schley, N. D., Olack, G. W., Incarvito, C. D., Brudvig, G. W., & Crabtree, R. H. (2011). Anodic deposition of a robust iridium-based water-oxidation catalyst from organometallic precursors. Chemical Science, 2(1), 94-98. | en_US |
dc.identifier.uri | http://hdl.handle.net/1808/21211 | |
dc.description.abstract | Artificial photosynthesis, modeled on natural light-driven oxidation of water in Photosystem II, holds promise as a sustainable source of reducing equivalents for producing fuels. Few robust water-oxidation catalysts capable of mediating this difficult four-electron, four-proton reaction have yet been described. We report a new method for generating an amorphous electrodeposited material, principally consisting of iridium and oxygen, which is a robust and long-lived catalyst for water oxidation, when driven electrochemically. The catalyst material is generated by a simple anodic deposition from Cp*Ir aqua or hydroxo complexes in aqueous solution. This work suggests that organometallic precursors may be useful in electrodeposition of inorganic heterogeneous catalysts. | en_US |
dc.publisher | Royal Society of Chemistry | en_US |
dc.rights | This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/). | en_US |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/ | |
dc.title | Anodic deposition of a robust iridium-based water-oxidation catalyst from organometallic precursors | en_US |
dc.type | Article | en_US |
kusw.kuauthor | Blakemore, James D. | |
kusw.kudepartment | Chemistry | en_US |
dc.identifier.doi | 10.1039/C0SC00418A | en_US |
kusw.oaversion | Scholarly/refereed, publisher version | en_US |
kusw.oapolicy | This item meets KU Open Access policy criteria. | en_US |
dc.rights.accessrights | openAccess |