Cycloaddition reaction of furan with Si(100)-2×1

Qiao, Ming Hua; Tao, Franklin Feng; Cao, Y.; Li, Z. H.; Dai, W. L.; Deng, J. F.; Xu, Guo Qin

dc.contributor.author	Qiao, Ming Hua
dc.contributor.author	Tao, Franklin Feng
dc.contributor.author	Cao, Y.
dc.contributor.author	Li, Z. H.
dc.contributor.author	Dai, W. L.
dc.contributor.author	Deng, J. F.
dc.contributor.author	Xu, Guo Qin
dc.date.accessioned	2015-11-20T20:29:56Z
dc.date.available	2015-11-20T20:29:56Z
dc.date.issued	2001
dc.identifier.citation	Qiao, M. H., F. Tao, Y. Cao, Z. H. Li, W. L. Dai, J. F. Deng, and G. Q. Xu. "Cycloaddition Reaction of Furan with Si(100)-2×1." The Journal of Chemical Physics J. Chem. Phys. 114.6 (2001): 2766. http://dx.doi.org/10.1063/1.1338477	en_US
dc.identifier.uri	http://hdl.handle.net/1808/18960
dc.description	This is the published version. Copyright 2001 American Institute of Physics	en_US
dc.description.abstract	The adsorption configuration of furan on Si(100)-2×1 at 125 K has been investigated using x-ray photoelectron spectroscopy(XPS), ultraviolet photoelectron spectroscopy (UPS), high resolution electron energy loss spectroscopy (HREELS), and semiempirical molecular orbital (MO) calculation. A chemisorbed furan species is identified, which does not desorb until 300 K. Our results clearly demonstrate the covalent attachment of furan onto Si(100), possibly through a [4+2] cycloaddition reaction. Based on the frontier molecular orbital (FMO) theory and work function measurements, an electron donation mechanism from furan to Si(100)-2×1 is proposed to be involved in the cycloaddition reaction.	en_US
dc.publisher	American Institute of Physics	en_US
dc.subject	X-ray photoelectron spectroscopy	en_US
dc.subject	Adsorption	en_US
dc.subject	Chemical reaction theory	en_US
dc.subject	Chemical reaction	en_US
dc.subject	Desorption	en_US
dc.title	Cycloaddition reaction of furan with Si(100)-2×1	en_US
dc.type	Article
kusw.kuauthor	TAo, Franklin Feng
kusw.kudepartment	Chemical & Petroleum Engr	en_US
dc.identifier.doi	10.1063/1.1338477
kusw.oaversion	Scholarly/refereed, publisher version
kusw.oapolicy	This item does not meet KU Open Access policy criteria.
dc.rights.accessrights	openAccess

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