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Cycloaddition reaction of furan with Si(100)-2×1
| dc.contributor.author | Qiao, Ming Hua | |
| dc.contributor.author | Tao, Franklin Feng | |
| dc.contributor.author | Cao, Y. | |
| dc.contributor.author | Li, Z. H. | |
| dc.contributor.author | Dai, W. L. | |
| dc.contributor.author | Deng, J. F. | |
| dc.contributor.author | Xu, Guo Qin | |
| dc.date.accessioned | 2015-11-20T20:29:56Z | |
| dc.date.available | 2015-11-20T20:29:56Z | |
| dc.date.issued | 2001 | |
| dc.identifier.citation | Qiao, M. H., F. Tao, Y. Cao, Z. H. Li, W. L. Dai, J. F. Deng, and G. Q. Xu. "Cycloaddition Reaction of Furan with Si(100)-2×1." The Journal of Chemical Physics J. Chem. Phys. 114.6 (2001): 2766. http://dx.doi.org/10.1063/1.1338477 | en_US |
| dc.identifier.uri | http://hdl.handle.net/1808/18960 | |
| dc.description | This is the published version. Copyright 2001 American Institute of Physics | en_US |
| dc.description.abstract | The adsorption configuration of furan on Si(100)-2×1 at 125 K has been investigated using x-ray photoelectron spectroscopy(XPS), ultraviolet photoelectron spectroscopy (UPS), high resolution electron energy loss spectroscopy (HREELS), and semiempirical molecular orbital (MO) calculation. A chemisorbed furan species is identified, which does not desorb until 300 K. Our results clearly demonstrate the covalent attachment of furan onto Si(100), possibly through a [4+2] cycloaddition reaction. Based on the frontier molecular orbital (FMO) theory and work function measurements, an electron donation mechanism from furan to Si(100)-2×1 is proposed to be involved in the cycloaddition reaction. | en_US |
| dc.publisher | American Institute of Physics | en_US |
| dc.subject | X-ray photoelectron spectroscopy | en_US |
| dc.subject | Adsorption | en_US |
| dc.subject | Chemical reaction theory | en_US |
| dc.subject | Chemical reaction | en_US |
| dc.subject | Desorption | en_US |
| dc.title | Cycloaddition reaction of furan with Si(100)-2×1 | en_US |
| dc.type | Article | |
| kusw.kuauthor | TAo, Franklin Feng | |
| kusw.kudepartment | Chemical & Petroleum Engr | en_US |
| dc.identifier.doi | 10.1063/1.1338477 | |
| kusw.oaversion | Scholarly/refereed, publisher version | |
| kusw.oapolicy | This item does not meet KU Open Access policy criteria. | |
| dc.rights.accessrights | openAccess |
