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Entropy of electrolytes
dc.contributor.author | Laird, Brian Bostian | |
dc.contributor.author | Haymet, A. D. J. | |
dc.date.accessioned | 2014-12-17T18:51:26Z | |
dc.date.available | 2014-12-17T18:51:26Z | |
dc.date.issued | 1994-01-01 | |
dc.identifier.citation | Laird, Brian B.; Haymet, A. D. J. (1994). "Entropy of electrolytes." The Journal of Chemical Physics, 100(5):3775-3779. http://dx.doi.org/10.1063/1.466365 | |
dc.identifier.issn | 0021-9606 | |
dc.identifier.uri | http://hdl.handle.net/1808/16153 | |
dc.description | This is the publisher's version, also available electronically from http://scitation.aip.org/content/aip/journal/jcp/100/5/10.1063/1.466365 | |
dc.description.abstract | The entropy of 1–1 and 2–2 model electrolytes is calculated from an expansion in terms of the multiparticle correlation functions. For electrolytes, a simple truncation of this expansion is never sufficient for the accurate calculation of the entropy,even in the limit of low concentration, in marked contrast to the behavior for short‐ranged potentials. However, a partial, but infinite‐order, summation of the expansion is shown to yield both the correct low‐concentration limit and excellent results over a wide range of concentrations for both 1–1 and 2–2 electrolytes. The consequences of this result for some earlier applications of the entropy expansion to electrolytes are discussed. | |
dc.publisher | American Institute of Physics | |
dc.title | Entropy of electrolytes | |
dc.type | Article | |
kusw.kuauthor | Laird, Brian Bostian | |
kusw.kudepartment | Chemistry | |
dc.identifier.doi | 10.1063/1.466365 | |
kusw.oaversion | Scholarly/refereed, publisher version | |
kusw.oapolicy | This item does not meet KU Open Access policy criteria. | |
dc.rights.accessrights | openAccess |