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    Translational energy dependence of reaction mechanism: Xe++CH4→XeH++CH3

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    HierlP_JCP_1981(74)5082.pdf (853.2Kb)
    Issue Date
    1981-01-01
    Author
    Miller, G. D.
    Strattan, L. W.
    Cole, C. L.
    Hierl, Peter M.
    Publisher
    American Institute of Physics
    Type
    Article
    Article Version
    Scholarly/refereed, publisher version
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    Abstract
    The dynamics of the exoergic ion–molecule reaction Xe+(CH4,CH3)XeH+ were studied by chemical accelerator techniques over the relative translational energy range 0.2 to 8 eV. Results of the kinematicmeasurements are reported as scattering intensity contour maps in Cartesian velocity space. Center‐of‐mass angular and energy distributions, derived from these maps, provide information on the reaction mechanism and on the partitioning of available energy between internal and translational modes in the products. The results suggest that reaction proceeds via the formation of a long‐lived complex at low collision energies (below 0.5 eV) and by a direct mechanism approaching spectator stripping at higher energies.
    Description
    This is the publisher's version, also available electronically from http://scitation.aip.org/content/aip/journal/jcp/74/9/10.1063/1.441715.
    URI
    http://hdl.handle.net/1808/16092
    DOI
    https://doi.org/10.1063/1.441715
    ISSN
    0021-9606
    Collections
    • Chemistry Scholarly Works [610]
    Citation
    Miller, G. D.; Strattan, L. W.; Cole, C. L.; Hierl, Peter M. (1981). "Translational energy dependence of reaction mechanism: Xe++CH4→XeH++CH3." Jounal of Chemical Physics, 74:5082. http://dx.doi.org/10.1063/1.441715.

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    Contact KU ScholarWorks
    785-864-8983
    KU Libraries
    1425 Jayhawk Blvd
    Lawrence, KS 66045
    785-864-8983

    KU Libraries
    1425 Jayhawk Blvd
    Lawrence, KS 66045
    Image Credits
     

     

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