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    Role of impact parameter in branching reactions: Chemical accelerator studies of the reaction Xe++CH4→XeCH3 ++H

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    HierlP_JCP_1981(74)5093.pdf (522.8Kb)
    Issue Date
    1981-01-01
    Author
    Miller, G. D.
    Strattan, L. W.
    Hierl, Peter M.
    Publisher
    American Institute of Physics
    Type
    Article
    Article Version
    Scholarly/refereed, publisher version
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    Abstract
    Integral reaction cross sections and product velocity distributions have been measured for the ion–molecule reaction Xe+(CH4,H)XeCH3 + over the relative reactant translational energy range of 0.7–5.5 eV by chemical accelerator techniques. The kinematic results indicate that reaction proceeds in a direct manner by a rebound mechanism over the energy range studied, suggesting that this substitution reaction occurs predominantly in small impact parameter collisions. This finding contrasts with the results obtained for the competing reaction, Xe+(CH4,CH3)XeH+, where the strong forward scattering of the XeH+ product indicates that H‐atom abstraction occurs primarily in large impact parameter collisions.
    Description
    This is the publisher's version, also available electronically from http://scitation.aip.org/content/aip/journal/jcp/74/9/10.1063/1.441716.
    URI
    http://hdl.handle.net/1808/16091
    DOI
    https://doi.org/10.1063/1.441716
    ISSN
    0021-9606
    Collections
    • Chemistry Scholarly Works [610]
    Citation
    Miller, G. D.; Strattan, L. W.; Hierl, P. M. (1981.). "Role of impact parameter in branching reactions: Chemical accelerator studies of the reaction Xe++CH4→XeCH3 ++H ." Jounal of Chemical Physics, 74:5093-5099. http://dx.doi.org/10.1063/1.441716.

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    Contact KU ScholarWorks
    785-864-8983
    KU Libraries
    1425 Jayhawk Blvd
    Lawrence, KS 66045
    785-864-8983

    KU Libraries
    1425 Jayhawk Blvd
    Lawrence, KS 66045
    Image Credits
     

     

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