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dc.contributor.authorHierl, Peter M.
dc.contributor.authorPaulson, John F.
dc.date.accessioned2014-12-15T15:50:16Z
dc.date.available2014-12-15T15:50:16Z
dc.date.issued1984
dc.identifier.citationHierl, Peter M.; Paulson, John F. (1984). "Translational energy dependence of cross sections for reactions of OH− (H2O) n with CO2 and SO2." Journal of Chemical Physics, 80:4890. http://dx.doi.org/10.1063/1.446510
dc.identifier.issn0021-9606
dc.identifier.urihttp://hdl.handle.net/1808/16090
dc.descriptionThis is the publisher's version, also available electronically from http://scitation.aip.org/content/aip/journal/jcp/80/10/10.1063/1.446510.
dc.description.abstractA tandem mass spectrometer has been used to measure cross sections for reactions of the solvated negative ions OH−(H2O) n , where 0≤n≤3, with the neutral molecules CO2 and SO2 over the range of reactant translational energy 0.15–25.0 eV (LAB). The reactions observed include solvent switching, collisional dissociation, and charge transfer. The exoergic solvent switching reactions are very rapid, having cross sections which exceed a hundred square Angstroms at low energies. These cross sections decrease approximately as (energy)−0.5 up to 1 eV and then decrease much more rapidly at higher collision energies. Estimates of bond dissociation energies for the cluster ions are derived from the measured translational energy thresholds for the endothermic collisional dissociationreactions.
dc.publisherAmerican Institute of Physics
dc.titleTranslational energy dependence of cross sections for reactions of OH− (H2O) n with CO2 and SO2
dc.typeArticle
kusw.kuauthorHierl, Peter M.
kusw.kudepartmentChemistry
dc.identifier.doi10.1063/1.446510
kusw.oaversionScholarly/refereed, publisher version
kusw.oapolicyThis item does not meet KU Open Access policy criteria.
dc.rights.accessrightsopenAccess


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