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    Studies of rotational predissociation of van der Waals molecule by the method of complex coordinate

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    Chu_Studies_of_Rotational_Predissociation.pdf (545.9Kb)
    Issue Date
    1980-01-01
    Author
    Chu, Shih-I
    Publisher
    Elsevier
    Type
    Article
    Article Version
    Scholarly/refereed, publisher version
    Metadata
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    Abstract
    A practical method is presented for calculating resonance energies and widths (lifetimes) of metastable states of van der Waals molecules, incorporating the use of complex coordinate transformation and square‐integrable basis functions. The utility of the method is illustrated through a study of the level widths and energies of rotationally predissociating atom–diatom model systems. Satisfactory agreement with previous works was found. Besides involving only bound state calculations and being free from imposement of boundary conditions, the method can be readily extendable to multichannel coupling problems.
    Description
    This is the published version, also available here: http://dx.doi.org/10.1063/1.439812.
    URI
    http://hdl.handle.net/1808/15869
    DOI
    https://doi.org/10.1063/1.439812
    Collections
    • Chemistry Scholarly Works [613]
    Citation
    Chu, Shih-I. "Studies of rotational predissociation of van der Waals molecule by the method of complex coordinate." The Journal of Chemical Physics 72, 4772 (1980); http://dx.doi.org/10.1063/1.439812.

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    785-864-8983

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    Contact KU ScholarWorks
    785-864-8983
    KU Libraries
    1425 Jayhawk Blvd
    Lawrence, KS 66045
    785-864-8983

    KU Libraries
    1425 Jayhawk Blvd
    Lawrence, KS 66045
    Image Credits
     

     

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