dc.contributor.author | Green, Steffan | |
dc.contributor.author | Binder, Thomas | |
dc.contributor.author | Hagberg, Erik | |
dc.contributor.author | Subramaniam, Bala | |
dc.date.accessioned | 2023-05-31T16:04:57Z | |
dc.date.available | 2023-05-31T16:04:57Z | |
dc.date.issued | 2022-12-19 | |
dc.identifier.citation | Green, S., Binder, T., Hagberg, E., & Subramaniam, B. (2022). Correlation between Lignin-Carbohydrate Complex Content in Grass Lignins and Phenolic Aldehyde Production by Rapid Spray Ozonolysis. ACS engineering Au, 3(2), 84–90. https://doi.org/10.1021/acsengineeringau.2c00041 | en_US |
dc.identifier.uri | https://hdl.handle.net/1808/34246 | |
dc.description.abstract | We provide strong evidence that the amounts of phenolic aldehydes (vanillin and p-hydroxybenzaldehyde, pHB) selectively released during rapid ozonolysis of grass lignins are correlated with the unsubstituted aryl carbons of lignin–carbohydrate complexes present in these lignins. In the case of acetosolv lignin from corn stover, we observed a steady yield of vanillin and pHB (cumulatively ∼5 wt % of the initial lignin). We demonstrate the continuous ozonolysis of the lignin in a spray reactor at ambient temperature and pressure. In sharp contrast, similar ozonolysis of acetosolv lignin from corn cobs resulted in a twofold increase in the combined yield (∼10 wt %) of vanillin and pHB. Structural analysis with 1H–13C heteronuclear single quantum coherence (HSQC) nuclear magnetic resonance revealed that signals assigned to unsubstituted aryl carbons of lignin–carbohydrate complexes are quantitatively correlated to phenolic aldehyde production from spray ozonolysis. The ratios of the integrated peak volumes corresponding to coumarates and ferulates in the HSQC spectra of cob and corn stover lignins (SLs) are 2.4 and 2.0, respectively. These ratios are nearly identical to the observed 2.3-fold increase in pHB and 1.8-fold increase in vanillin production rates from corn cob lignin compared to corn SL. Considering that the annual U.S. lignin capacity from these grass lignin sources is ∼60 million MT, the value creation potential from these flavoring agents is conservatively ∼$50 million annually from just 10% of the lignin. These new insights into structure/product correlation and spray reactor characteristics provide rational guidance for developing viable technologies to valorize grass lignins. | en_US |
dc.publisher | American Chemical Society | en_US |
dc.rights | Copyright © 2022 The Authors. Published by American Chemical Society. This article is distributed under the terms of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0). | en_US |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | en_US |
dc.subject | Grass lignin structure | en_US |
dc.subject | HSQC-NMR | en_US |
dc.subject | Valorization | en_US |
dc.subject | Spray ozonolysis | en_US |
dc.subject | Flavorings | en_US |
dc.title | Correlation between Lignin–Carbohydrate Complex Content in Grass Lignins and Phenolic Aldehyde Production by Rapid Spray Ozonolysis | en_US |
dc.type | Article | en_US |
kusw.kuauthor | Green, Steffan | |
kusw.kuauthor | Binder, Thomas | |
kusw.kuauthor | Hagberg, Erik | |
kusw.kuauthor | Subramaniam, Bala | |
kusw.kudepartment | Center for Environmentally Beneficial Catalysis | en_US |
kusw.kudepartment | Chemical and Petroleum Engineering | en_US |
dc.identifier.doi | 10.1021/acsengineeringau.2c00041 | en_US |
dc.identifier.orcid | https://orcid.org/0000-0002-0128-6288 | en_US |
dc.identifier.orcid | https://orcid.org/0000-0001-5361-1954 | en_US |
kusw.oaversion | Scholarly/refereed, publisher version | en_US |
kusw.oapolicy | This item meets KU Open Access policy criteria. | en_US |
dc.identifier.pmid | PMC10119922 | en_US |
dc.rights.accessrights | openAccess | en_US |