Using the factors of soil formation to assess stable carbon isotope disequilibrium in late Pleistocene (MIS 3) buried soils of the Great Plains, North America

Abstract

The stable carbon isotope composition of both soil organic matter (SOM) and pedogenic carbonate are widely used as paleoenvironmental proxies. This study utilizes δ13C analyses to reconstruct bioclimatic change from a series of buried soils in the central Great Plains of North America that developed between ca. 44–24 ka. Results revealed a paradoxical isotopic disequilibrium between the isotopic composition of bulk SOM (δ13CSOM) and pedogenic carbonate (δ13Ccarb). Specifically, Δ13C values are 0.1 to 6.3 per mil greater than the highest expected equilibrium value of 17 per mil in the Bk horizons. In contrast, Δ13C values are 0.1 to 4.8 per mil lower than the lowest expected equilibrium value of 14 per mil in the Ak horizons. A soil-forming factor approach was utilized to establish multiple working hypotheses regarding the influence of climate, vegetation, parent material, and time on the observed isotopic disequilibrium.

Of the various hypotheses presented, we suggest that the following most likely explain the observed isotopic disequilibrium. The greater-than-expected Δ13C values in the Bk horizons most likely reflects seasonal bias in pedogenic carbonate formation, resulting in an apparent C4-biased signal. The lower-than-expected Δ13C values in the Ak horizons remains perplexing. The most likely explanation is that detrital carbonate contributions affected the δ13Ccarb record or that the δ13Ccarb and δ13CSOM records are asynchronous. Overall, it appears that different factors have affected the δ13CSOM and δ13Ccarb records independently and therefore results of this study highlight the importance of assessing pedogenic carbonates for isotopic equilibrium as well as the need to understand past environmental conditions (i.e., soil-forming factors) when interpreting isotopic trends.