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Engineered Nanoparticles with Decoupled Photocatalysis and Wettability for Membrane-Based Desalination and Separation of Oil-Saline Water Mixtures
dc.contributor.author | Shrestha, Bishwash | |
dc.contributor.author | Ezazi, Mohammadamin | |
dc.contributor.author | Kwon, Gibum | |
dc.date.accessioned | 2021-12-10T19:29:18Z | |
dc.date.available | 2021-12-10T19:29:18Z | |
dc.date.issued | 2021-05-05 | |
dc.identifier.citation | Shrestha, B.; Ezazi, M.; Kwon, G. Engineered Nanoparticles with Decoupled Photocatalysis and Wettability for Membrane-Based Desalination and Separation of Oil-Saline Water Mixtures. Nanomaterials 2021, 11, 1397. https://doi.org/10.3390/nano11061397 | en_US |
dc.identifier.uri | http://hdl.handle.net/1808/32280 | |
dc.description.abstract | Membrane-based separation technologies are the cornerstone of remediating unconventional water sources, including brackish and industrial or municipal wastewater, as they are relatively energy-efficient and versatile. However, membrane fouling by dissolved and suspended substances in the feed stream remains a primary challenge that currently prevents these membranes from being used in real practices. Thus, we directly address this challenge by applying a superhydrophilic and oleophobic coating to a commercial membrane surface which can be utilized to separate and desalinate an oil and saline water mixture, in addition to photocatalytically degrading the organic substances. We fabricated the photocatalytic membrane by coating a commercial membrane with an ultraviolet (UV) light-curable adhesive. Then, we sprayed it with a mixture of photocatalytic nitrogen-doped titania (N-TiO2) and perfluoro silane-grafted silica (F-SiO2) nanoparticles. The membrane was placed under a UV light, which resulted in a chemically heterogeneous surface with intercalating high and low surface energy regions (i.e., N-TiO2 and F-SiO2, respectively) that were securely bound to the commercial membrane surface. We demonstrated that the coated membrane could be utilized for continuous separation and desalination of an oil–saline water mixture and for simultaneous photocatalytic degradation of the organic substances adsorbed on the membrane surface upon visible light irradiation. | en_US |
dc.publisher | MDPI | en_US |
dc.rights | © 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license. | en_US |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | en_US |
dc.subject | Photocatalytic nanoparticles | en_US |
dc.subject | Wettability | en_US |
dc.subject | Perfluorinated silica nanoparticles | en_US |
dc.subject | Oil–water separation | en_US |
dc.subject | Membrane fouling | en_US |
dc.title | Engineered Nanoparticles with Decoupled Photocatalysis and Wettability for Membrane-Based Desalination and Separation of Oil-Saline Water Mixtures | en_US |
dc.type | Article | en_US |
kusw.kuauthor | Shrestha, Bishwash | |
kusw.kuauthor | Ezazi, Mohammadamin | |
kusw.kuauthor | Kwon, Gibum | |
kusw.kudepartment | Mechanical Engineering | en_US |
dc.identifier.doi | 10.3390/nano11061397 | en_US |
dc.identifier.orcid | https://orcid.org/ 0000-0003-0045-8890 | en_US |
dc.identifier.orcid | https://orcid.org/ 0000-0003-2284-9809 | en_US |
dc.identifier.orcid | https://orcid.org/ 0000-0002-7192-1910 | en_US |
kusw.oaversion | Scholarly/refereed, publisher version | en_US |
kusw.oapolicy | This item meets KU Open Access policy criteria. | en_US |
dc.identifier.pmid | PMC8227411 | en_US |
dc.rights.accessrights | openAccess | en_US |