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Photocatalytic Aminodecarboxylation of Carboxylic Acids
Lang, Simon Bouyea Cartwright, Kaitie C. Welter, Richard S. Locascio, Theresa M. Tunge, Jon A.
Lang, Simon Bouyea
Cartwright, Kaitie C.
Welter, Richard S.
Locascio, Theresa M.
Tunge, Jon A.
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Abstract
Aminodecarboxylation of unactivated alkyl carboxylic acids has been accomplished utilizing an organic photocatalyst. This operationally simple reaction utilizes readily available carboxylic acids to chemoselectively generate reactive alkyl intermediates that are not accessible via conventional two-electron pathways. The organic radical intermediates are efficiently trapped with electrophilic diazo compounds to provide aminated alkanes.
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Date
2016-07
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Publisher
Wiley
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Research Projects
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Keywords
Homogenous catalysis, Photocatalysis, Amination, Carboxylic acids
Citation
Lang, S. B., Cartwright, K. C., Welter, R. S., Locascio, T. M., & Tunge, J. A. (2016). Photocatalytic Aminodecarboxylation of Carboxylic Acids. European Journal of Organic Chemistry, 2016(20), 3331–3334. http://doi.org/10.1002/ejoc.201600620