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    Stereodivergent Synthesis of Enantioenriched 4-Hydroxy-2- cyclopentenones

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    Aubé_2014.pdf (372.2Kb)
    Issue Date
    2014-01-03
    Author
    Singh, Gurpreet
    Meyer, Angelica Michelle
    Aubé, Jeffrey
    Publisher
    American Chemical Society
    Type
    Article
    Article Version
    Scholarly/refereed, author accepted manuscript
    Rights
    This document is the Accepted Manuscript version of a Published Work that appeared in final form in the Journal of Organic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/jo402539p.
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    Abstract
    Protected 4-hydroxycyclopentenones (4-HCPs) constitute an important class of intermediates in chemical synthesis. A route to this class of compound has been developed. Key steps include Noyori reduction (which establishes the stereochemistry of the product), ring-closing metathesis, and simple functional group conversions to provide a set of substituted 4-HCPs in either enantiomeric form.
    URI
    http://hdl.handle.net/1808/23677
    DOI
    https://doi.org/10.1021/jo402539p
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    • Medicinal Chemistry Scholarly Works [225]
    Citation
    Singh, G., Meyer, A., & Aubé, J. (2014). Stereodivergent Synthesis of Enantioenriched 4-Hydroxy-2-cyclopentenones. The Journal of Organic Chemistry, 79(1), 452–458. http://doi.org/10.1021/jo402539p

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    Contact KU ScholarWorks
    785-864-8983
    KU Libraries
    1425 Jayhawk Blvd
    Lawrence, KS 66045
    785-864-8983

    KU Libraries
    1425 Jayhawk Blvd
    Lawrence, KS 66045
    Image Credits
     

     

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