Divalent and Multivalent Activation in Phosphate Triesters: A Versatile Method for the Synthesis of Advanced Polyol Synthons

Thomas, Christopher Daniel; McParland, James P.; Hanson, Paul R.

dc.contributor.author	Thomas, Christopher Daniel
dc.contributor.author	McParland, James P.
dc.contributor.author	Hanson, Paul R.
dc.date.accessioned	2017-06-12T19:07:03Z
dc.date.available	2017-06-12T19:07:03Z
dc.date.issued	2009-11
dc.identifier.citation	Thomas, C. D., McParland, J. P. and Hanson, P. R. (2009), Divalent and Multivalent Activation in Phosphate Triesters: A Versatile Method for the Synthesis of Advanced Polyol Synthons. Eur. J. Org. Chem., 2009: 5487–5500. doi:10.1002/ejoc.200900560	en_US
dc.identifier.uri	http://hdl.handle.net/1808/24470
dc.description	This is the peer reviewed version of the following article: Thomas, C. D., McParland, J. P. and Hanson, P. R. (2009), Divalent and Multivalent Activation in Phosphate Triesters: A Versatile Method for the Synthesis of Advanced Polyol Synthons. Eur. J. Org. Chem., 2009: 5487–5500. doi:10.1002/ejoc.200900560, which has been published in final form at http://doi.org/10.1002/ejoc.200900560. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.	en_US
dc.description.abstract	The construction of mono- and bicyclic phosphate trimesters possessing divalent and multivalent activation and their subsequent use in the production of advanced polyol synthons is presented. The method highlights efforts to employ phosphate tethers as removable, functionally active tethers capable of multipositional activation and their subsequent role as leaving groups in selective cleavage reactions. The development of phosphate tethers represents an integrated platform for a new and versatile tether for natural product synthesis and sheds light on new approaches to the facile construction of small molecules.	en_US
dc.publisher	Wiley	en_US
dc.subject	Phosphate	en_US
dc.subject	Protecting groups	en_US
dc.subject	Cuprates	en_US
dc.subject	Metathesis	en_US
dc.subject	Tether	en_US
dc.title	Divalent and Multivalent Activation in Phosphate Triesters: A Versatile Method for the Synthesis of Advanced Polyol Synthons	en_US
dc.type	Article	en_US
kusw.kuauthor	Thomas, Christopher D.
kusw.kuauthor	McParland, James P.
kusw.kuauthor	Hanson, Paul R.
kusw.kudepartment	Chemistry	en_US
dc.identifier.doi	10.1002/ejoc.200900560	en_US
kusw.oaversion	Scholarly/refereed, publisher version	en_US
kusw.oapolicy	This item meets KU Open Access policy criteria.	en_US
dc.identifier.pmid	PMC3526009	en_US
dc.rights.accessrights	openAccess

Files in this item

Name:: Thomas_2009.pdf
Size:: 12.36Mb
Format:: PDF

View/Open

This item appears in the following Collection(s)

The University of Kansas prohibits discrimination on the basis of race, color, ethnicity, religion, sex, national origin, age, ancestry, disability, status as a veteran, sexual orientation, marital status, parental status, gender identity, gender expression and genetic information in the University’s programs and activities. The following person has been designated to handle inquiries regarding the non-discrimination policies: Director of the Office of Institutional Opportunity and Access, IOA@ku.edu, 1246 W. Campus Road, Room 153A, Lawrence, KS, 66045, (785)864-6414, 711 TTY.