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    Rate constants for the reactions of O+ with N2 and O2 as a function of temperature (300–1800 K)

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    HierlPeter_JCP_1997(106)3540.pdf (82.98Kb)
    Issue Date
    1997-01-01
    Author
    Hierl, Peter M.
    Dotan, I.
    Seeley, John V.
    Doren, Jane M. Van
    Morris, Robert A.
    Viggiano, A. A.
    Publisher
    American Institute of Physics
    Type
    Article
    Article Version
    Scholarly/refereed, publisher version
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    Abstract
    We have studied the rate constants for the reaction of O+ with N2 over the temperature range 300–1600 K and the reaction of O+ with O2 over the range 300 to 1800 K. The results are in good agreement with previous measurements made up to 900 K. The rate constant for the O+reaction with N2 shows a minimum in the temperature range 1100–1300 K. The increase above this temperature is due to N2 v=2 becoming populated. The rate constant for O++O2 shows a minimum in the 800–1100 K range. Comparing to previous drift tube measurements allows the rate constant for O2 (v>0) to be derived. The v>0 rate constant is approximately five times larger than the v=0 rate constant.
    Description
    This is the publisher's version, also available electronically from http://scitation.aip.org/content/aip/journal/jcp/106/9/10.1063/1.473450.
    URI
    http://hdl.handle.net/1808/16089
    DOI
    https://doi.org/10.1063/1.473450
    ISSN
    0021-9606
    Collections
    • Chemistry Scholarly Works [552]
    Citation
    Hierl, Peter M. et al. (1997). "Rate constants for the reactions of O+ with N2 and O2 as a function of temperature (300–1800 K)." Journal of Chemical Physics, 106:3540-3544. http://dx.doi.org/10.1063/1.473450.

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    Contact KU ScholarWorks
    785-864-8983
    KU Libraries
    1425 Jayhawk Blvd
    Lawrence, KS 66045
    785-864-8983

    KU Libraries
    1425 Jayhawk Blvd
    Lawrence, KS 66045
    Image Credits
     

     

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