dc.contributor.author | Wyatt, J. R. | |
dc.contributor.author | Strattan, L. W. | |
dc.contributor.author | Chivalak, S. | |
dc.contributor.author | Hierl, Peter M. | |
dc.date.accessioned | 2014-12-15T17:54:04Z | |
dc.date.available | 2014-12-15T17:54:04Z | |
dc.date.issued | 1975-01-01 | |
dc.identifier.citation | Wyatt, J. R.; Strattan, L. W.; Chivalak, S.; Hierl, Peter M. (1975). "Excitation functions for the reactions of Ar^+ with CH4, CD4, and CH2D2." Jounal of Chemical Physics, 63:4582-4591. http://dx.doi.org/10.1063/1.431267 | |
dc.identifier.issn | 4582-4591 | |
dc.identifier.uri | http://hdl.handle.net/1808/16099 | |
dc.description | This is the publisher's version, also available electronically from http://scitation.aip.org/content/aip/journal/jcp/63/11/10.1063/1.431267. | |
dc.description.abstract | Integral reaction cross sections as a function of initial translational energy (0.4–30 eV c.m.) are reported for isotopic variants of the exoergic ion‐molecule reaction Ar++CH4 → ArH++CH3. The excitation functions, which maximize at about 5 eV and decrease at lower collision energies, appear to possess translational energy thresholds at about 0.1 eV. At the higher energies there is a large isotope effect favoring abstraction of H over D. The observed threshold behavior, unusual for exoergic reactions of positive ions, is discussed in terms of the formation of an ArCH4 + intermediate complex at low collision energies. | |
dc.publisher | American Institute of Physics | |
dc.title | Excitation functions for the reactions of Ar^+ with CH4, CD4, and CH2D2 | |
dc.type | Article | |
kusw.kuauthor | Wyatt, J. R. | |
kusw.kuauthor | Strattan, L. W. | |
kusw.kuauthor | Chivalak, S. | |
kusw.kuauthor | Hierl, Peter M. | |
kusw.kudepartment | Chemistry | |
dc.identifier.doi | 10.1063/1.431267 | |
kusw.oaversion | Scholarly/refereed, publisher version | |
kusw.oapolicy | This item does not meet KU Open Access policy criteria. | |
dc.rights.accessrights | openAccess | |