Pahadi, Nirmal K.Tunge, Jon A.2017-01-052017-01-052009-07-30Pahadi, Nirmal, and Jon Tunge. "Catalytic Intermolecular Hydroamination of Vinyl Ethers." Synlett 2009.19 (2009): 3135-138.https://hdl.handle.net/1808/22457This manuscript details the development of a palladium-catalyzed hydroamination of vinyl ethers. It is proposed that palladium catalyzes the hydroamination via Brønsted base catalysis, where palladium is protonated by the relatively acidic sulfonamide to generate a palladium hydride as well as the active anionic sulfonamide nucleophile. Thus, this process is distinct from known palladium-catalyzed hydroaminations of styrene derivatives that utilize less acidic amines.HydroaminationVinyl etherPalladiumSulfonamideArticle10.1055/s-0029-1218293openAccess