Rolfe, AlanLoh, Joanna K.Maity, Pradip K.Hanson, Paul R.2017-03-232017-03-232011-01-07Rolfe, A., Loh, J. K., Maity, P. K., & Hanson, P. R. (2011). High-Load, Hybrid Si-ROMP Reagents. Organic Letters, 13(1), 4–7. http://doi.org/10.1021/ol102239hhttps://hdl.handle.net/1808/23473The combination of norbornenyl-tagged (Nb-tagged) silica particles and functionalized Nb-tagged monomers for the generation of hybrid Si-ROMP reagents and scavengers is reported. Specifically Si-ROMP-derived bis-acid chloride, dichlorotriazine and triphenylphosphine scavenger/reagents have been grafted from the surface of silica particles utilizating surface-initiated, ring-opening metathesis polymerization (ROMP). These hybridpolymeric materials combine the physical properties of current immobilized silica reagents and represent a key advancement in load by merging the inherent tunable properties of the ROMP-derived oligomers with silica supports for application in parallel synthesis.This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/ol102239hArticle10.1021/ol102239hopenAccess