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{\*\listoverridetable{\listoverride\listid67122019\listoverridecount0\ls1}}{\info{\title TABLES}{\author Alex Yokochi & George Sheldrick}{\operator Victor Day}{\creatim\yr2007\mo6\dy25\hr12\min29}{\revtim\yr2008\mo1\dy28\min30}
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\fs24\lang1033\langfe1033\cgrid\langnp1033\langfenp1033 {\f1\fs28 Structure k27b\tab \tab 
\par Sample pHP - pH\tab \tab 
\par }\pard \qc \li0\ri0\nowidctlpar\faauto\rin0\lin0\itap0 {\f1\fs28 
\par 
\par 
\par 
\par 
\par 
\par 
\par 
\par 
\par Crystal Structure Report 
\par 
\par for 
\par 
\par }{\b\f1\fs28 C}{\b\f1\fs28\sub 15}{\b\f1\fs28 H}{\b\f1\fs28\sub 12}{\b\f1\fs28 O}{\b\f1\fs28\sub 4}{\b\f1\fs28 
\par }{\f1\fs28 
\par Professor Rich Givens 
\par 
\par Beth Cope
\par 
\par 
\par 
\par 
\par 
\par 
\par 
\par 
\par 
\par 
\par 
\par 
\par January 27, 2007
\par \page }{\f1\fs20  }{\b\f1 Contents }{\f1 
\par }\pard \ql \li0\ri0\nowidctlpar\tx6315\faauto\rin0\lin0\itap0 {\f1 \tab 
\par }\pard\plain \s15\ql \li0\ri0\nowidctlpar\tqr\tx7200\faauto\rin0\lin0\itap0 \fs24\lang1033\langfe1033\cgrid\langnp1033\langfenp1033 {\f1 Figure 1.  50% Probability Ellipsoid Drawing of Molecule ... \'85....    3
\par }\pard\plain \ql \li0\ri0\nowidctlpar\tqr\tx7200\faauto\rin0\lin0\itap0 \fs24\lang1033\langfe1033\cgrid\langnp1033\langfenp1033 {\f1 Figure 2.  Packing Diagram ..........................................\'85\'85\'85.\'85\tab  12
\par Comments .............................................................\'85\'85\'85\'85\'85.\'85\tab 15
\par Experimental .........................................................\'85\'85\'85\'85\'85\'85.\tab 15
\par Acknowledgements .....................................................\'85\'85\'85\'85..\tab 16
\par References ...........................................................\'85\'85\'85\'85\'85\'85..\tab 16
\par Table 1.  Crystal Data ...............................................\'85\'85\'85\'85\'85.\tab 17
\par Table 2.  Atom Coordinates for Nonhydrogen Atoms......\'85\'85\'85\'85 18
\par Table 3.  Bond Lengths \'85\'85\'85\'85\'85\'85.................................\'85..\'85.\tab 19
\par Table 4.  Bond Angles \'85\'85\'85\'85\'85\'85\'85................................\'85\'85.. \tab 20
\par Table 5.  Nonhydrogen Anisotropic Displacement Parameters ..   21
\par Table 6.  Hydrogen Atom Parameters .................................\'85....\tab  22
\par Table 7.  Torsion Angles .............................................\'85\'85.\'85\'85.\tab  23
\par Table 8.  Hydrogen Bond Geometries .................................\'85\'85.\tab  24
\par 
\par Appendix: 
\par Table 9.  Structure Factors ..........................................\'85\'85\'85\'85..\tab  1
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dd1b5409e71b4d09ed1b4a09f71b4809011c4809071c4a09111c4d091a1c5409211c5a09271c64092b1c6e092c1c74092c1c7e092b1c8409271c8e09211c9809
1a1c9e09111ca409071ca809011ca909f71ba909ed1ba809e71ba409dd1b9e09d71b98093800000025031a002a0d1e16240d24161a0d2b16100d2e160a0d3016
000d3016fa0c2e16f00c2b16e60c2416e00c1e16d90c1416d60c0b16d50c0416d50cfa15d60cf415d90cea15e00ce115e60cda15f00cd415fa0cd015000dcf15
0a0dcf15100dd0151a0dd415240dda152a0de11508000000250302002a0dcf152a0d301608000000fa0200000000000000000000040000002d01000004000000f001020007000000fc020000ffffff000000040000002d01020004000000f0010100040000002701ffff03000000000000000000}}{\f1\fs20 \page }{
\b\f1\fs20 Comments
\par }{\f1\fs20 \tab The asymmetric unit contains one C}{\f1\fs20\sub 15}{\f1\fs20 H}{\f1\fs20\sub 12}{\f1\fs20 O}{\f1\fs20\sub 4 }{\f1\fs20 molecule.  All displacement ellipsoids are drawn at the 50% probability level.
\par }\pard \ql \li0\ri0\sl360\slmult1\nowidctlpar\tx4240\tx6800\tx8500\tx10200\tx11900\faauto\rin0\lin0\itap0 {\f1\fs20 
\par }\pard\plain \s18\ql \li0\ri0\sl360\slmult1\nowidctlpar\tx4240\tx6800\tx8500\tx10200\tx11900\faauto\rin0\lin0\itap0 \b\f1\fs20\lang1033\langfe1033\cgrid\langnp1033\langfenp1033 {
Brief  Experimental Description to be Included as Text or as a Footnote at Time of Publication
\par }\pard\plain \ql \li0\ri0\sl360\slmult1\nowidctlpar\faauto\rin0\lin0\itap0 \fs24\lang1033\langfe1033\cgrid\langnp1033\langfenp1033 {\f1\fs20 \tab Colorless crystals of C}{\f1\fs20\sub 15}{\f1\fs20 H}{\f1\fs20\sub 12}{\f1\fs20 O}{\f1\fs20\sub 4 }{\f1\fs20 
are, at 100(2) K, orthorhombic, space group P2}{\f1\fs20\sub 1}{\f1\fs20 2}{\f1\fs20\sub 1}{\f1\fs20 2}{\f1\fs20\sub 1}{\f1\fs20  \endash  D}{\f1\fs20\sub 2}{\f1\fs20\super 4}{\f1\fs20  (No. 19) (1) with }{\b\f1\fs20 a}{\f1\fs20  = 8.470(1) \'c5, }{
\b\f1\fs20 b}{\f1\fs20  = 9.844(1) \'c5, }{\b\f1\fs20 c}{\f1\fs20  = 14.474(2) \'c5, V = 1206.8(3) \'c5}{\f1\fs20\super 3}{\f1\fs20  and Z =  4 molecules \{d}{\f1\fs20\sub calcd }{\f1\fs20 = 1.410 g/cm}{\f1\fs20\super 3}{\f1\fs20 ; }{\f1\fs20 
{\field{\*\fldinst SYMBOL 109 \\f "Symbol" \\s 10}{\fldrslt\f3\fs20}}}{\f1\fs20\sub a}{\f1\fs20 (MoK}{\f1\fs20 {\field{\*\fldinst SYMBOL 97 \\f "Symbol" \\s 10}{\fldrslt\f3\fs20}}}{\f1\fs20 ) = 0.103 mm}{\f1\fs20\super -1}{\f1\fs20 \}
.   A full hemisphere of diffracted intensities (1850 10-second frames with a }{\f1\fs20 {\field{\*\fldinst SYMBOL 119 \\f "Symbol" \\s 10}{\fldrslt\f3\fs20}}}{\f1\fs20  scan width of 0.30}{\f1\fs20 {\field{\*\fldinst SYMBOL 176 \\f "Symbol"
 \\s 10}{\fldrslt\f3\fs20}}}{\f1\fs20 ) was measured for a single-domain specimen using graphite-monochromated MoK}{\f1\fs20 {\field{\*\fldinst SYMBOL 97 \\f "Symbol" \\s 10}{\fldrslt\f3\fs20}}}{\f1\fs20  radiation (}{\f1\fs20 {\field{\*\fldinst SYMBOL
 108 \\f "Symbol" \\s 10}{\fldrslt\f3\fs20}}}{\f1\fs20 = 0.71073 \'c5
) on a Bruker SMART APEX CCD Single Crystal Diffraction System (2).  X-rays were provided by a fine-focus sealed x-ray tube operated at 50kV and 30mA.  Lattice constants were determined with th
e Bruker SAINT software package using peak centers for 1901 reflections.  A total of 14702 integrated reflection intensities having 2}{\f1\fs20 {\field{\*\fldinst SYMBOL 113 \\f "Symbol" \\s 10}{\fldrslt\f3\fs20}}}{\f1\fs20 ((MoK}{\f1\fs20 
{\field{\*\fldinst SYMBOL 97 \\f "Symbol" \\s 10}{\fldrslt\f3\fs20}}}{\f1\fs20 )< 61.14}{\f1\fs20 {\field{\*\fldinst SYMBOL 176 \\f "Symbol" \\s 10}{\fldrslt\f3\fs20}}}{\f1\fs20  were produced
 using the Bruker program SAINT(3); 3686 of these were unique and gave R}{\f1\fs20\sub int}{\f1\fs20 
 = 0.056 with a coverage which was 99.9% complete. The data were corrected empirically for variable absorption effects using equivalent reflections; the relative transmission factor
s ranged from 0.877 to 1.000.  The Bruker software package SHELXTL was used to solve the structure using \'93direct methods\'94 techniques.  All stages of weighted full-matrix least-squares refinement were conducted using F}{\f1\fs20\sub o}{
\f1\fs20\super 2 }{\f1\fs20 data with the SHELXTL Version 6.10 software package(4). 
\par }\pard \ql \li0\ri720\sl360\slmult1\nowidctlpar\tx720\tx1152\tx1872\tx4240\tx6800\tx8500\tx10200\tx11900\faauto\rin720\lin0\itap0 {\f1\fs20 \tab 
The final structural model incorporated anisotropic thermal parameters for all nonhydrogen atoms and isotropic thermal parameters for all hydrogen atoms.  All hydrogen atoms were located in a difference Fourier and included in the str
uctural model as independent isotropic atoms whose parameters were allowed to vary in least-squares refinement cycles.  A total of 220 parameters were refined using no restraints, 3686 data and weights of w = 1/ [}{\f1\fs20 {\field{\*\fldinst SYMBOL
 115 \\f "Symbol" \\s 10}{\fldrslt\f3\fs20}}}{\f1\fs20\up6\super 2}{\f1\fs20 (F}{\f1\fs20\up6\super 2}{\f1\fs20 ) + (0.0648 P)}{\f1\fs20\up6\super 2}{\f1\fs20  + 0.2445 P], where P = [F}{\f1\fs20\dn6 o}{\f1\fs20\up6\super 2}{\f1\fs20  + 2F}{\f1\fs20\dn6 c
}{\f1\fs20\up6\super 2}{\f1\fs20 ] / 3.  Final agreement factors at convergence are:  R}{\f1\fs20\sub 1}{\f1\fs20 (unweighted, based on F) = 0.066 for 2836 independent absorption-corrected \'93observed\'94 reflections having 2}{\f1\fs20 
{\field{\*\fldinst SYMBOL 113 \\f "Symbol" \\s 10}{\fldrslt\f3\fs20}}}{\f1\fs20 (MoK}{\f1\fs20 {\field{\*\fldinst SYMBOL 97 \\f "Symbol" \\s 10}{\fldrslt\f3\fs20}}}{\f1\fs20 )<  61.14}{\f1\fs20 {\field{\*\fldinst SYMBOL 176 \\f "Symbol" \\s 10}{\fldrslt
\f3\fs20}}}{\f1\fs20  and I>2}{\f1\fs20 {\field{\*\fldinst SYMBOL 115 \\f "Symbol" \\s 10}{\fldrslt\f3\fs20}}}{\f1\fs20 (I);  R}{\f1\fs20\sub 1}{\f1\fs20 (unweighted, based on F) = 0.089 and wR}{\f1\fs20\sub 2}{\f1\fs20 (weighted, based on F}{
\f1\fs20\super 2}{\f1\fs20 ) = 0.148 for all 3686 independent absorption-corrected reflections having 2}{\f1\fs20 {\field{\*\fldinst SYMBOL 113 \\f "Symbol" \\s 10}{\fldrslt\f3\fs20}}}{\f1\fs20 (MoK}{\f1\fs20 {\field{\*\fldinst SYMBOL 97 \\f "Symbol"
 \\s 10}{\fldrslt\f3\fs20}}}{\f1\fs20 )< 61.14}{\f1\fs20 {\field{\*\fldinst SYMBOL 176 \\f "Symbol" \\s 10}{\fldrslt\f3\fs20}}}{\f1\fs20 
.  The largest shift/s.u. was 0.000 in the final refinement cycle.  The final difference map had maxima and minima of 0.39 and -0.32 e}{\f1\fs20\super -}{\f1\fs20 /\'c5}{\f1\fs20\up6\super 3}{\f1\fs20 , respectively.  Since the \'93Flack\'94
 parameter refined to a final value of 0.0(14), the absolute structure could not be reliably determined experimentally using anomalous dispersion of the x-rays.
\par 
\par \page 
\par }\pard \ql \li0\ri0\sl360\slmult1\nowidctlpar\tx0\tx720\tx4240\tx6800\tx8500\tx10200\tx11900\faauto\rin0\lin0\itap0 {\f1\fs20    
\par  }{\b\f1\fs20 Acknowledgment
\par }\pard \ql \li0\ri0\sl360\slmult0\nowidctlpar\tx0\tx720\tx4240\tx6800\tx8500\tx10200\tx11900\faauto\rin0\lin0\itap0 {\f1\fs20 \tab 
The authors thank the National Science Foundation (grant CHE-0079282) and the University of Kansas for funds to purchase the  x-ray instrument and computers.  
\par }\pard \ql \li60\ri0\sl360\slmult0\nowidctlpar\tx4240\tx6800\tx8500\tx10200\tx11900\faauto\rin0\lin60\itap0 {\f1\fs20 
\par }\pard\plain \s2\ql \li60\ri0\sl360\slmult0\keepn\nowidctlpar\tx4240\tx6800\tx8500\tx10200\tx11900\faauto\outlinelevel1\rin0\lin60\itap0 \b\f1\fs20\lang1033\langfe1033\cgrid\langnp1033\langfenp1033 {References
\par }\pard\plain \ql \li0\ri0\widctlpar\aspalpha\aspnum\faauto\adjustright\rin0\lin0\itap0 \fs24\lang1033\langfe1033\cgrid\langnp1033\langfenp1033 {
\par {\listtext\pard\plain\f1\fs20 \hich\af1\dbch\af0\loch\f1 (1)\tab}}\pard \ql \fi-360\li420\ri0\sl360\slmult1\nowidctlpar\jclisttab\tx420\tx4240\tx6800\tx8500\tx10200\tx11900\faauto\ls1\rin0\lin420\itap0 {\f1\fs20 
 International Tables for Crystallography, Vol A, 4}{\f1\fs20\super th}{\f1\fs20  ed., Kluwer:  Boston (1996). 
\par {\listtext\pard\plain\f1\fs20 \hich\af1\dbch\af0\loch\f1 (2)\tab}Data Collection:  SMART Software Reference Manual (1998). Bruker-AXS, 5465 E. Cheryl Parkway, Madison, WI  53711-5373  USA.   
\par {\listtext\pard\plain\f1\fs20 \hich\af1\dbch\af0\loch\f1 (3)\tab}Data Reduction:  SAINT Software Reference Manual (1998). Bruker-AXS, 6300 Enterprise Dr., Madison, WI 53719-1173, USA. 
\par {\listtext\pard\plain\f1\fs20 \hich\af1\dbch\af0\loch\f1 (4)\tab}G. M. Sheldrick (2000). SHELXTL Version 6.10 Reference Manual. Bruker-AXS, 5465 E. Cheryl Parkway, Madison, WI  53711-5373 USA.  
\par }\pard \ql \li0\ri0\sl360\slmult0\nowidctlpar\tx4240\tx6800\tx8500\tx10200\tx11900\faauto\rin0\lin0\itap0 {\page }{\f1\fs20 Table 1.  Crystal data and structure refinement for C}{\f1\fs20\sub 15}{\f1\fs20 H}{\f1\fs20\sub 12}{\f1\fs20 O}{\f1\fs20\sub 4}{
\f1\fs20 .
\par Empirical formula \tab C}{\f1\fs20\sub 15}{\f1\fs20 H}{\f1\fs20\sub 12}{\f1\fs20 O}{\f1\fs20\sub 4}{\f1\fs20 
\par Formula weight \tab 256.25
\par Temperature \tab 100(2) K
\par Wavelength \tab 0.71073 \'c5
\par Crystal system \tab Orthorhombic
\par Space group \tab P2}{\f1\fs20\sub 1}{\f1\fs20 2}{\f1\fs20\sub 1}{\f1\fs20 2}{\f1\fs20\sub 1}{\f1\fs20  \endash  D}{\f1\fs20\sub 2}{\f1\fs20\super 4}{\f1\fs20  (No. 19)
\par Unit cell dimensions\tab }{\b\f1\fs20 a}{\f1\fs20  =  8.470(1) \'c5\tab }{\b\f44\fs20 \'e1}{\f1\fs20  = 90.000\'b0
\par \tab }{\b\f1\fs20 b}{\f1\fs20  =  9.844(1) \'c5\tab }{\b\f44\fs20 \'e2}{\f1\fs20  = 90.000\'b0
\par \tab }{\b\f1\fs20 c}{\f1\fs20  = 14.474(2) \'c5\tab }{\b\f44\fs20 \'e3  }{\f1\fs20 = 90.000\'b0
\par Volume\tab 1206.8(3) \'c5}{\f1\fs20\super 3}{\f1\fs20 
\par Z\tab 4
\par Density (calculated)\tab 1.410 Mg/m}{\f1\fs20\super 3}{\f1\fs20 
\par Absorption coefficient\tab 0.103 mm}{\f1\fs20\up6 -1}{\f1\fs20 
\par F(000)\tab 536
\par Crystal size\tab 0.38 x 0.10 x 0.06 mm}{\f1\fs20\super 3
\par }{\f1\fs20 Theta range for data collection\tab 2.50\'b0 to 30.57\'b0
\par Index ranges\tab -12 \u8804\'3d h \u8804\'3d 12, -14 \u8804\'3d k \u8804\'3d 14, -20 \u8804\'3d l \u8804\'3d 20
\par Reflections collected\tab 14702
\par Independent reflections\tab 3686 [R}{\f1\fs20\sub int}{\f1\fs20  = 0.056]
\par Completeness to theta = 30.57\'b0\tab 99.9 % 
\par Absorption correction\tab Empirical
\par Max. and min. transmission\tab 1.000 and 0.877
\par Refinement method\tab Full-matrix least-squares on F}{\f1\fs20\super 2}{\f1\fs20 
\par Data / restraints / parameters\tab 3686 / 0 / 220
\par Goodness-of-fit on F}{\f1\fs20\super 2}{\f1\fs20 \tab 1.059
\par Final R indices [I>2sigma(I)]\tab R}{\f1\fs20\sub 1}{\f1\fs20  = 0.066, wR}{\f1\fs20\sub 2}{\f1\fs20  = 0.138
\par R indices (all data)\tab R}{\f1\fs20\sub 1}{\f1\fs20  = 0.089, wR}{\f1\fs20\sub 2}{\f1\fs20  = 0.148
\par Absolute structure parameter\tab 0.0(14)
\par Largest diff. peak and hole\tab 0.39 and -0.32 e}{\f1\fs20\super -}{\f1\fs20 /\'c5}{\f1\fs20\super 3}{\f1\fs20 
\par ________________________________________________________________________________
\par R}{\f1\fs20\sub 1}{\f1\fs20  = }{\f1\fs20 {\field{\*\fldinst SYMBOL 83 \\f "Symbol" \\s 10}{\fldrslt\f3\fs20}}}{\f1\fs20  ||F}{\f1\fs20\dn6 o}{\f1\fs20 | - |F}{\f1\fs20\dn6 c}{\f1\fs20 || / }{\f1\fs20 {\field{\*\fldinst SYMBOL 83 \\f "Symbol"
 \\s 10}{\fldrslt\f3\fs20}}}{\f1\fs20  |F}{\f1\fs20\dn6 o}{\f1\fs20 | 
\par }\pard \ql \li0\ri0\sl360\slmult0\nowidctlpar\tqc\tx2880\tqc\tx4320\tqc\tx5760\tqc\tx7200\tx11900\faauto\rin0\lin0\itap0 {\f1\fs20 wR}{\f1\fs20\sub 2}{\f1\fs20  = \{ }{\f1\fs20 {\field{\*\fldinst SYMBOL 83 \\f "Symbol" \\s 10}{\fldrslt\f3\fs20}}}{
\f1\fs20  [w(F}{\f1\fs20\dn6 o}{\f1\fs20\up6\super 2}{\f1\fs20  - F}{\f1\fs20\dn6 c}{\f1\fs20\up6\super 2}{\f1\fs20 )}{\f1\fs20\up6\super 2}{\f1\fs20 ] / }{\f1\fs20 {\field{\*\fldinst SYMBOL 83 \\f "Symbol" \\s 10}{\fldrslt\f3\fs20}}}{\f1\fs20  [w(F}{
\f1\fs20\dn6 o}{\f1\fs20\up6\super 2}{\f1\fs20 )}{\f1\fs20\up6\super 2}{\f1\fs20 ] \}}{\f1\fs20\up6\super 1}{\f1\fs20 \page Table 2.  Atomic coordinates  ( x 10}{\f1\fs20\super 4}{\f1\fs20 ) and equivalent  isotropic displacement parameters (\'c5}{
\f1\fs20\super 2 }{\f1\fs20 x 10}{\f1\fs20\super 3}{\f1\fs20 )
\par for C}{\f1\fs20\sub 15}{\f1\fs20 H}{\f1\fs20\sub 12}{\f1\fs20 O}{\f1\fs20\sub 4}{\f1\fs20 . U(eq) is defined as one third of  the trace of the orthogonalized U}{\f1\fs20\sub ij}{\f1\fs20  tensor.
\par ________________________________________________________________________________ 
\par \tab x\tab y\tab z\tab U(eq)
\par }\pard \ql \li0\ri0\sl360\slmult0\nowidctlpar\tqdec\tx2880\tqdec\tx4320\tqdec\tx5760\tqdec\tx7200\tx11900\faauto\rin0\lin0\itap0 {\f1\fs20 ________________________________________________________________________________  
\par O(1)\tab 272(2)\tab 2447(2)\tab 1206(1)\tab 28(1)
\par O(2)\tab 1937(2)\tab 4199(2)\tab 1413(1)\tab 34(1)
\par O(3)\tab -1523(2)\tab 4245(2)\tab 2047(1)\tab 30(1)
\par O(4)\tab -1518(2)\tab 3811(2)\tab 6427(1)\tab 30(1)
\par C(1)\tab 1191(3)\tab 3468(2)\tab 900(2)\tab 26(1)
\par C(2)\tab 157(3)\tab 2343(3)\tab 2192(2)\tab 27(1)
\par C(3)\tab -888(3)\tab 3447(2)\tab 2574(2)\tab 22(1)
\par C(4)\tab -1098(3)\tab 3522(2)\tab 3587(2)\tab 21(1)
\par C(5)\tab -2051(3)\tab 4532(2)\tab 3967(2)\tab 23(1)
\par C(6)\tab -2211(3)\tab 4657(2)\tab 4914(2)\tab 23(1)
\par C(7)\tab -1402(3)\tab 3767(2)\tab 5497(1)\tab 21(1)
\par C(8)\tab -450(3)\tab 2756(3)\tab 5125(2)\tab 27(1)
\par C(9)\tab -297(3)\tab 2630(2)\tab 4182(2)\tab 25(1)
\par C(10)\tab 1175(3)\tab 3584(2)\tab -124(2)\tab 24(1)
\par C(11)\tab 2028(3)\tab 4629(3)\tab -522(2)\tab 29(1)
\par C(12)\tab 2007(3)\tab 4800(3)\tab -1473(2)\tab 33(1)
\par C(13)\tab 1154(3)\tab 3917(3)\tab -2026(2)\tab 29(1)
\par C(14)\tab 306(3)\tab 2855(3)\tab -1626(2)\tab 29(1)
\par C(15)\tab 312(3)\tab 2686(2)\tab -674(2)\tab 24(1)
\par }\pard \ql \li0\ri0\sl360\slmult0\nowidctlpar\tqdec\tx2880\tx11900\faauto\rin0\lin0\itap0 {\f1\fs20 ________________________________________________________________________________ \page Table 3.   Bond lengths [\'c5] for C}{\f1\fs20\sub 15}{\f1\fs20 H}{
\f1\fs20\sub 12}{\f1\fs20 O}{\f1\fs20\sub 4}{\f1\fs20 .
\par ________________________________________________________________________________ 
\par \sect }\sectd \psz1\sbknone\linex0\cols2\sectdefaultcl \pard\plain \ql \li0\ri0\sl360\slmult0\nowidctlpar\tqdec\tx2880\tx11900\faauto\rin0\lin0\itap0 \fs24\lang1033\langfe1033\cgrid\langnp1033\langfenp1033 {\f1\fs20 O(1)-C(1) \tab 1.346(3)
\par O(1)-C(2) \tab 1.433(3)
\par O(2)-C(1) \tab 1.212(3)
\par O(3)-C(3) \tab 1.221(3)
\par O(4)-C(7) \tab 1.351(3)
\par O(4)-H(4O) \tab 0.97(5)
\par C(1)-C(10) \tab 1.487(3)
\par C(2)-C(3) \tab 1.508(3)
\par C(2)-H(2A) \tab 1.00(3)
\par C(2)-H(2B) \tab 0.97(3)
\par C(3)-C(4) \tab 1.478(3)
\par C(4)-C(5) \tab 1.394(3)
\par C(4)-C(9) \tab 1.404(3)
\par C(5)-C(6) \tab 1.382(3)
\par C(5)-H(5) \tab 0.94(3)
\par C(6)-C(7) \tab 1.396(3)
\par C(6)-H(6) \tab 0.91(3)
\par C(7)-C(8) \tab 1.390(3)
\par C(8)-C(9) \tab 1.377(3)
\par C(8)-H(8) \tab 1.00(3)
\par C(9)-H(9) \tab 0.96(3)
\par C(10)-C(11) \tab 1.383(3)
\par C(10)-C(15) \tab 1.397(3)
\par C(11)-C(12) \tab 1.388(3)
\par C(11)-H(11) \tab 0.90(3)
\par C(12)-C(13) \tab 1.384(4)
\par C(12)-H(12) \tab 0.98(3)
\par C(13)-C(14) \tab 1.394(4)
\par C(13)-H(13) \tab 0.99(2)
\par C(14)-C(15) \tab 1.387(3)
\par C(14)-H(14) \tab 1.07(4)
\par C(15)-H(15) \tab 0.90(3)\sect }\sectd \psz1\sbknone\linex0\sectdefaultcl \pard\plain \ql \li0\ri0\sl360\slmult0\nowidctlpar\tqdec\tx2880\tx11900\faauto\rin0\lin0\itap0 \fs24\lang1033\langfe1033\cgrid\langnp1033\langfenp1033 {\f1\fs20 
________________________________________________________________________________ 
\par 
\par \page Table 4.   Bond angles [\'b0] for C}{\f1\fs20\sub 15}{\f1\fs20 H}{\f1\fs20\sub 12}{\f1\fs20 O}{\f1\fs20\sub 4}{\f1\fs20 .
\par ________________________________________________________________________________ 
\par \sect }\sectd \psz1\sbknone\linex0\cols2\sectdefaultcl \pard\plain \ql \li0\ri0\sl360\slmult0\nowidctlpar\tqdec\tx2880\tx11900\faauto\rin0\lin0\itap0 \fs24\lang1033\langfe1033\cgrid\langnp1033\langfenp1033 {\f1\fs20 C(1)-O(1)-C(2)\tab 114.8(2)
\par C(7)-O(4)-H(4O)\tab 114(3)
\par O(2)-C(1)-O(1)\tab 123.0(2)
\par O(2)-C(1)-C(10)\tab 124.7(2)
\par O(1)-C(1)-C(10)\tab 112.3(2)
\par O(1)-C(2)-C(3)\tab 110.7(2)
\par O(1)-C(2)-H(2A)\tab 108(1)
\par C(3)-C(2)-H(2A)\tab 112(2)
\par O(1)-C(2)-H(2B)\tab 105(2)
\par C(3)-C(2)-H(2B)\tab 112(2)
\par H(2A)-C(2)-H(2B)\tab 109(2)
\par O(3)-C(3)-C(4)\tab 122.4(2)
\par O(3)-C(3)-C(2)\tab 119.5(2)
\par C(4)-C(3)-C(2)\tab 118.1(2)
\par C(5)-C(4)-C(9)\tab 118.9(2)
\par C(5)-C(4)-C(3)\tab 119.8(2)
\par C(9)-C(4)-C(3)\tab 121.2(2)
\par C(6)-C(5)-C(4)\tab 120.8(2)
\par C(6)-C(5)-H(5)\tab 118(2)
\par C(4)-C(5)-H(5)\tab 121(2)
\par C(5)-C(6)-C(7)\tab 119.7(2)
\par C(5)-C(6)-H(6)\tab 117(2)
\par C(7)-C(6)-H(6)\tab 123(2)
\par O(4)-C(7)-C(8)\tab 116.8(2)
\par O(4)-C(7)-C(6)\tab 123.2(2)
\par C(8)-C(7)-C(6)\tab 120.0(2)
\par C(9)-C(8)-C(7)\tab 120.2(2)
\par C(9)-C(8)-H(8)\tab 122(2)
\par C(7)-C(8)-H(8)\tab 118(2)
\par C(8)-C(9)-C(4)\tab 120.4(2)
\par C(8)-C(9)-H(9)\tab 120(2)
\par C(4)-C(9)-H(9)\tab 119(2)
\par C(11)-C(10)-C(15)\tab 120.4(2)
\par C(11)-C(10)-C(1)\tab 117.9(2)
\par C(15)-C(10)-C(1)\tab 121.7(2)
\par C(10)-C(11)-C(12)\tab 119.8(2)
\par C(10)-C(11)-H(11)\tab 121(2)
\par C(12)-C(11)-H(11)\tab 119(2)
\par C(13)-C(12)-C(11)\tab 120.3(3)
\par C(13)-C(12)-H(12)\tab 123(2)
\par C(11)-C(12)-H(12)\tab 117(2)
\par C(12)-C(13)-C(14)\tab 120.0(2)
\par C(12)-C(13)-H(13)\tab 122(1)
\par C(14)-C(13)-H(13)\tab 117(1)
\par C(15)-C(14)-C(13)\tab 120.0(2)
\par C(15)-C(14)-H(14)\tab 119(2)
\par C(13)-C(14)-H(14)\tab 121(2)
\par C(14)-C(15)-C(10)\tab 119.5(2)
\par C(14)-C(15)-H(15)\tab 122(2)
\par C(10)-C(15)-H(15)\tab 119(2)
\par \sect }\sectd \psz1\sbknone\linex0\sectdefaultcl \pard\plain \ql \li0\ri0\sl360\slmult0\nowidctlpar\tqdec\tx2880\tx11900\faauto\rin0\lin0\itap0 \fs24\lang1033\langfe1033\cgrid\langnp1033\langfenp1033 {\f1\fs20 
________________________________________________________________________________: 
\par  
\par }\pard \ql \li0\ri0\sl360\slmult0\nowidctlpar\tqc\tx1200\tqc\tx2400\tqc\tx3600\tqc\tx4800\tqc\tx6000\tqc\tx7200\tx8400\faauto\rin0\lin0\itap0 {\f1\fs20 \page  Table 5.   Anisotropic displacement parameters  (\'c5}{\f1\fs20\super 2}{\f1\fs20\up6  }{
\f1\fs20 x 10}{\f1\fs20\super 3}{\f1\fs20 ) for C}{\f1\fs20\sub 15}{\f1\fs20 H}{\f1\fs20\sub 12}{\f1\fs20 O}{\f1\fs20\sub 4}{\f1\fs20 . The anisotropic
\par displacement factor exponent takes the form:  -2}{\f1\fs20 {\field{\*\fldinst SYMBOL 112 \\f "Symbol" \\s 10}{\fldrslt\f3\fs20}}}{\f1\fs20\super 2}{\f1\fs20 [ h}{\f1\fs20\super 2}{\f1\fs20  a*}{\f1\fs20\super 2}{\f1\fs20 U}{\f1\fs20\sub 11 }{\f1\fs20 
+ ...  + 2 h k a* b* U}{\f1\fs20\sub 12}{\f1\fs20  ]
\par ______________________________________________________________________________ 
\par \tab U}{\f1\fs20\sub 11}{\f1\fs20 \tab U}{\f1\fs20\sub 22 }{\f1\fs20 \tab U}{\f1\fs20\sub 33}{\f1\fs20 \tab U}{\f1\fs20\sub 23}{\f1\fs20 \tab U}{\f1\fs20\sub 13}{\f1\fs20 \tab U}{\f1\fs20\sub 12}{\f1\fs20 
\par ______________________________________________________________________________ 
\par O(1)\tab 43(1) \tab 25(1)\tab 16(1) \tab -1(1)\tab -1(1) \tab 0(1)
\par O(2)\tab 39(1) \tab 42(1)\tab 20(1) \tab 0(1)\tab -5(1) \tab -9(1)
\par O(3)\tab 38(1) \tab 30(1)\tab 22(1) \tab 5(1)\tab -7(1) \tab 5(1)
\par O(4)\tab 35(1) \tab 38(1)\tab 18(1) \tab -4(1)\tab -1(1) \tab 6(1)
\par C(1)\tab 31(1) \tab 28(1)\tab 19(1) \tab 1(1)\tab -1(1) \tab 0(1)
\par C(2)\tab 39(1) \tab 26(1)\tab 17(1) \tab 1(1)\tab -3(1) \tab 1(1)
\par C(3)\tab 25(1) \tab 22(1)\tab 19(1) \tab 2(1)\tab -2(1) \tab -3(1)
\par C(4)\tab 23(1) \tab 23(1)\tab 17(1) \tab 2(1)\tab 0(1) \tab 0(1)
\par C(5)\tab 25(1) \tab 21(1)\tab 24(1) \tab 3(1)\tab -2(1) \tab 0(1)
\par C(6)\tab 21(1) \tab 22(1)\tab 26(1) \tab 0(1)\tab 1(1) \tab 3(1)
\par C(7)\tab 21(1) \tab 25(1)\tab 17(1) \tab 2(1)\tab 0(1) \tab -1(1)
\par C(8)\tab 31(1) \tab 31(1)\tab 19(1) \tab 6(1)\tab 1(1) \tab 6(1)
\par C(9)\tab 30(1) \tab 24(1)\tab 22(1) \tab 4(1)\tab 1(1) \tab 6(1)
\par C(10)\tab 26(1) \tab 29(1)\tab 18(1) \tab 1(1)\tab -1(1) \tab 3(1)
\par C(11)\tab 31(1) \tab 32(1)\tab 24(1) \tab -3(1)\tab -4(1) \tab -2(1)
\par C(12)\tab 34(1) \tab 41(2)\tab 23(1) \tab 5(1)\tab 4(1) \tab 0(1)
\par C(13)\tab 28(1) \tab 43(1)\tab 17(1) \tab 4(1)\tab 0(1) \tab 5(1)
\par C(14)\tab 29(1) \tab 38(1)\tab 21(1) \tab -3(1)\tab 0(1) \tab 1(1)
\par C(15)\tab 26(1) \tab 28(1)\tab 20(1) \tab -1(1)\tab 0(1) \tab 2(1)
\par }\pard \ql \li0\ri0\sl360\slmult0\nowidctlpar\tqc\tx2880\tqc\tx4320\tqc\tx5760\tqc\tx7200\tx11900\faauto\rin0\lin0\itap0 {\f1\fs20 ______________________________________________________________________________ \page Table 6.   Hydrogen coordinates ( x 10}
{\f1\fs20\super 4}{\f1\fs20 ) and isotropic  displacement parameters (\'c5}{\f1\fs20\super 2}{\f1\fs20\up6  }{\f1\fs20 x 10}{\f1\fs20\super 3}{\f1\fs20 )
\par for C}{\f1\fs20\sub 15}{\f1\fs20 H}{\f1\fs20\sub 12}{\f1\fs20 O}{\f1\fs20\sub 4}{\f1\fs20 .
\par ________________________________________________________________________________ 
\par \tab x \tab y \tab z \tab U(eq)
\par ________________________________________________________________________________ 
\par }\pard \ql \li0\ri0\sl360\slmult0\nowidctlpar\tqdec\tx2880\tqdec\tx4320\tqdec\tx5760\tqdec\tx7200\tx11900\faauto\rin0\lin0\itap0 {\f1\fs20 H(4O)\tab -2200(70)\tab 4530(50)\tab 6660(30)\tab 130(20)
\par H(2A)\tab 1250(30)\tab 2380(30)\tab 2457(17)\tab 28(6)
\par H(2B)\tab -290(30)\tab 1450(30)\tab 2299(18)\tab 30(7)
\par H(5)\tab -2670(40)\tab 5100(30)\tab 3590(20)\tab 41(8)
\par H(6)\tab -2840(40)\tab 5350(30)\tab 5130(20)\tab 39(8)
\par H(8)\tab 110(30)\tab 2140(30)\tab 5560(20)\tab 43(8)
\par H(9)\tab 300(30)\tab 1900(30)\tab 3923(19)\tab 36(8)
\par H(11)\tab 2580(40)\tab 5220(30)\tab -170(20)\tab 36(8)
\par H(12)\tab 2610(30)\tab 5570(30)\tab -1722(19)\tab 32(7)
\par H(13)\tab 1300(30)\tab 3890(20)\tab -2704(16)\tab 17(6)
\par H(14)\tab -330(40)\tab 2150(40)\tab -2050(20)\tab 58(10)
\par H(15)\tab -240(30)\tab 2020(30)\tab -399(17)\tab 16(6)
\par }\pard \ql \li0\ri0\sl360\slmult0\nowidctlpar\tqc\tx5600\tx11900\faauto\rin0\lin0\itap0 {\f1\fs20 ________________________________________________________________________________ \page  Table 7.  Torsion angles [\'b0] for C}{\f1\fs20\sub 15}{\f1\fs20 H}{
\f1\fs20\sub 12}{\f1\fs20 O}{\f1\fs20\sub 4}{\f1\fs20 .
\par ________________________________________________________________________________ 
\par C(2)-O(1)-C(1)-O(2)\tab 4.0(3)
\par C(2)-O(1)-C(1)-C(10)\tab -176.01(19)
\par C(1)-O(1)-C(2)-C(3)\tab 74.5(3)
\par O(1)-C(2)-C(3)-O(3)\tab 1.7(3)
\par O(1)-C(2)-C(3)-C(4)\tab -178.0(2)
\par O(3)-C(3)-C(4)-C(5)\tab 0.0(3)
\par C(2)-C(3)-C(4)-C(5)\tab 179.8(2)
\par O(3)-C(3)-C(4)-C(9)\tab -177.0(2)
\par C(2)-C(3)-C(4)-C(9)\tab 2.7(3)
\par C(9)-C(4)-C(5)-C(6)\tab -0.1(3)
\par C(3)-C(4)-C(5)-C(6)\tab -177.2(2)
\par C(4)-C(5)-C(6)-C(7)\tab 0.4(3)
\par C(5)-C(6)-C(7)-O(4)\tab -178.9(2)
\par C(5)-C(6)-C(7)-C(8)\tab -0.4(3)
\par O(4)-C(7)-C(8)-C(9)\tab 178.8(2)
\par C(6)-C(7)-C(8)-C(9)\tab 0.2(4)
\par C(7)-C(8)-C(9)-C(4)\tab 0.1(4)
\par C(5)-C(4)-C(9)-C(8)\tab -0.1(3)
\par C(3)-C(4)-C(9)-C(8)\tab 177.0(2)
\par O(2)-C(1)-C(10)-C(11)\tab -2.3(4)
\par O(1)-C(1)-C(10)-C(11)\tab 177.6(2)
\par O(2)-C(1)-C(10)-C(15)\tab 178.6(2)
\par O(1)-C(1)-C(10)-C(15)\tab -1.4(3)
\par C(15)-C(10)-C(11)-C(12)\tab 1.1(4)
\par C(1)-C(10)-C(11)-C(12)\tab -178.0(2)
\par C(10)-C(11)-C(12)-C(13)\tab -0.9(4)
\par C(11)-C(12)-C(13)-C(14)\tab 0.3(4)
\par C(12)-C(13)-C(14)-C(15)\tab 0.3(4)
\par C(13)-C(14)-C(15)-C(10)\tab -0.2(4)
\par C(11)-C(10)-C(15)-C(14)\tab -0.5(4)
\par C(1)-C(10)-C(15)-C(14)\tab 178.6(2)
\par ________________________________________________________________________________ 
\par }\pard \ql \li0\ri0\sl360\slmult0\nowidctlpar\tqc\tx2880\tqc\tx4320\tqc\tx5760\tqc\tx7200\tqc\tx8640\tx11900\faauto\rin0\lin0\itap0 {\f1\fs20 Table 8.  Hydrogen bonds for C}{\f1\fs20\sub 15}{\f1\fs20 H}{\f1\fs20\sub 12}{\f1\fs20 O}{\f1\fs20\sub 4}{
\f1\fs20   [\'c5 and \'b0].
\par ____________________________________________________________________________ 
\par D-H...A\tab d(D-H)\tab d(H...A)\tab d(D...A)\tab <(DHA)
\par ____________________________________________________________________________ 
\par  O(4)-H(4O)...O(3)#1\tab 0.97(5)\tab 1.71(5)\tab 2.687(2)\tab 177(5)
\par ____________________________________________________________________________ 
\par Symmetry transformations used to generate equivalent atoms:  #1:  -x-1/2, -y+1, z+1/2.      
\par 
\par 
\par }}