Deacylative allylation of nitroalkanes: unsymmetric bisallylation via 3-component coupling

Grenning, Alexander J.; Tunge, Jon A.

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Issue Date

2011-02-11

Author

Grenning, Alexander J.

Tunge, Jon A.

Publisher

Wiley

Type

Article

Article Version

Scholarly/refereed, author accepted manuscript

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Abstract

Use it and lose it! Allylic alcohols were used directly for the synthesis of diallylated nitroalkanes in a three-component coupling based on the strategy of deacylative allylation for the in situ generation of a nucleophile and an allyl electrophile (see scheme).

Citation

Grenning, A. J., & Tunge, J. A. (2011). Deacylative allylation of nitroalkanes: unsymmetric bisallylation via 3-component coupling. Angewandte Chemie (International Ed. in English), 50(7), 1688–1691. http://doi.org/10.1002/anie.201006273

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