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    A Phosphate Tether-Mediated, One-pot, Sequential RCM/CM/Chemo-selective Hydrogenation Protocol

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    Issue Date
    2012-05-18
    Author
    Venukadasula, Phanindra K. M.
    Chegondi, Rambabu
    Suryn, Gregory M.
    Hanson, Paul R.
    Publisher
    American Chemical Society
    Type
    Article
    Article Version
    Scholarly/refereed, author accepted manuscript
    Rights
    This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/ol301007h
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    Abstract
    A versatile three-step, one-pot, sequential reaction protocol involving RCM, CM, and chemoselective hydrogenation is reported. This phosphate tether-mediated process occurs without intermediate isolation, is chemoselective and is governed by stereoelectronic properties innate to phosphate tethers, which ultimately act to preserve the integrity of the bisallylic, bicyclic phosphate for subsequent nucleophilic additions. Overall, this process can be used to efficiently generate advanced polyol synthons.
    URI
    http://hdl.handle.net/1808/23361
    DOI
    https://doi.org/10.1021/ol301007h
    Collections
    • Chemistry Scholarly Works [626]
    Citation
    Venukadasula, P. K. M., Chegondi, R., Suryn, G. M., & Hanson, P. R. (2012). A Phosphate Tether-Mediated, One-pot, Sequential RCM/CM/Chemo-selective Hydrogenation Protocol. Organic Letters, 14(10), 2634–2637. http://doi.org/10.1021/ol301007h

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    Contact KU ScholarWorks
    785-864-8983
    KU Libraries
    1425 Jayhawk Blvd
    Lawrence, KS 66045
    785-864-8983

    KU Libraries
    1425 Jayhawk Blvd
    Lawrence, KS 66045
    Image Credits
     

     

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