dc.contributor.advisor | Bowman-James, Kristin | |
dc.contributor.advisor | Malinakova, Helena C. | |
dc.contributor.author | Johnson, Thomas Seals | |
dc.date.accessioned | 2016-11-08T22:56:06Z | |
dc.date.available | 2016-11-08T22:56:06Z | |
dc.date.issued | 2016-05-31 | |
dc.date.submitted | 2016 | |
dc.identifier.other | http://dissertations.umi.com/ku:14702 | |
dc.identifier.uri | http://hdl.handle.net/1808/21852 | |
dc.description.abstract | The first project is described in Chapter 2, and details the synthesis of a series of mono- and multimetallic Pd(II) NNN-pincer complexes which—to the best of our knowledge—represent the first examples of these types of complexes being employed as catalysts in a Heck reaction. Chapter 3 discusses the design and synthesis of a hybrid pincer/imidazolium salt ligand and its transition metal chemistry, with the ultimate goal of synthesizing heterobimetallic complexes for bifunctional catalysis. The work in Chapter 4 strays away from the catalysis theme, and includes preliminary investigations into the synthesis of metal-organic frameworks (MOF) derived from the combination of a bis[palladium(II)] complex with a pyridine-appended ditopic macrocycle. | |
dc.format.extent | 263 pages | |
dc.language.iso | en | |
dc.publisher | University of Kansas | |
dc.rights | Copyright held by the author. | |
dc.subject | Chemistry | |
dc.subject | Inorganic chemistry | |
dc.subject | Organic chemistry | |
dc.subject | Catalysis | |
dc.subject | Heck Reaction | |
dc.subject | Heterobimetallic | |
dc.subject | Macrocycle | |
dc.subject | Palladium | |
dc.subject | Pincer | |
dc.title | Synthesis and Applications of Amide-Based Pd(II) NNN-pincer Complexes | |
dc.type | Thesis | |
dc.contributor.cmtemember | Tunge, Jon A. | |
dc.contributor.cmtemember | Prisinzano, Thomas E. | |
dc.thesis.degreeDiscipline | Chemistry | |
dc.thesis.degreeLevel | M.S. | |
dc.identifier.orcid | | |
dc.rights.accessrights | openAccess | |