dc.contributor.author | Elles, Christopher G. | |
dc.contributor.author | Shkrob, Ilya A. | |
dc.contributor.author | Crowell, Robert A. | |
dc.contributor.author | Arms, Dohn A. | |
dc.contributor.author | Landahl, Eric C. | |
dc.date.accessioned | 2014-12-10T18:25:47Z | |
dc.date.available | 2014-12-10T18:25:47Z | |
dc.date.issued | 2008-02-11 | |
dc.identifier.citation | Elles, Christopher G. (2008). "Transient x-ray absorption spectroscopy of hydrated halogen atom ." The Journal of Chemical Physics, 128:064402. http://dx.doi.org/10.1063/1.2827456. | |
dc.identifier.issn | 0021-9606 | |
dc.identifier.uri | http://hdl.handle.net/1808/16075 | |
dc.description | This is the publisher's version, also available electronically from http://scitation.aip.org/content/aip/journal/jcp/128/6/10.1063/1.2827456. | |
dc.description.abstract | Time-resolved x-ray absorption spectroscopy has been used to observe the transient species generated by one-photon detachment of an electron from aqueous bromide. The K-edge spectrum of the short-lived Br(0) atom exhibits a resonant 1s-4p transition that is absent for the Br− precursor. The strong 1s-4p resonance suggests that there is very little charge transfer from the solvent to the open-shell atom, whereas weak oscillations above the absorption edge indicate that the solvent shell around a neutral Br(0) atom is defined primarily by hydrophobic interactions. These conclusions are in agreement with Monte Carlo and quantum chemical simulations of the solvent structure. | |
dc.publisher | American Institute of Physics | |
dc.title | Transient x-ray absorption spectroscopy of hydrated halogen atom | |
dc.type | Article | |
kusw.kuauthor | Elles, Christopher G. | |
kusw.kudepartment | Chemistry | |
dc.identifier.doi | 10.1063/1.2827456 | |
kusw.oaversion | Scholarly/refereed, publisher version | |
kusw.oapolicy | This item does not meet KU Open Access policy criteria. | |
dc.rights.accessrights | openAccess | |