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ROMP-derived Oligomeric Phosphates for Application in Facile Benzylation
Long, Toby R. Maity, Pradip K. Samarakoon, Thiwanka Bandara Hanson, Paul R.
Long, Toby R.
Maity, Pradip K.
Samarakoon, Thiwanka Bandara
Hanson, Paul R.
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Abstract
The development of new ROMP-based oligomeric benzyl phosphates (OBPn) is reported for use as soluble, stable benzylating reagents. These oligomeric reagents are readily synthesized from commercially available materials and conveniently polymerized and purified in a one-pot process, affording bench stable, pure white, free-flowing solids on multi-gram scale. Utilization in benzylation reactions with a variety of nucleophiles is reported.
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2010-07-12
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American Chemical Society
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SamarakoonT_2010.pdf
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Long, T. R., Maity, P. K., Samarakoon, T. B., & Hanson, P. R. (2010). ROMP-derived Oligomeric Phosphates for Application in Facile Benzylation. Organic Letters, 12(13), 2904–2907. http://doi.org/10.1021/ol1006604