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Stereodivergent Synthesis of Enantioenriched 4-Hydroxy-2- cyclopentenones
Singh, Gurpreet Meyer, Angelica Michelle Aubé, Jeffrey
Singh, Gurpreet
Meyer, Angelica Michelle
Aubé, Jeffrey
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Abstract
Protected 4-hydroxycyclopentenones (4-HCPs) constitute an important class of intermediates in chemical synthesis. A route to this class of compound has been developed. Key steps include Noyori reduction (which establishes the stereochemistry of the product), ring-closing metathesis, and simple functional group conversions to provide a set of substituted 4-HCPs in either enantiomeric form.
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2014-01-03
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American Chemical Society
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Singh, G., Meyer, A., & Aubé, J. (2014). Stereodivergent Synthesis of Enantioenriched 4-Hydroxy-2-cyclopentenones. The Journal of Organic Chemistry, 79(1), 452–458. http://doi.org/10.1021/jo402539p