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Quinone-catalyzed oxidative deformylation: synthesis of imines from amino alcohols
Liu, Xinyun Phan, Johnny H. Haugeberg, Benjamin John Londhe, Shrikant S. Clift, Michael D.
Liu, Xinyun
Phan, Johnny H.
Haugeberg, Benjamin John
Londhe, Shrikant S.
Clift, Michael D.
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Abstract
A new method for imine synthesis by way of quinone-catalyzed oxidative deformylation of 1,2-amino alcohols is reported. A wide range of readily accessible amino alcohols and primary amines can be reacted to provide N-protected imine products. The methodology presented provides a novel organocatalytic approach for imine synthesis and demonstrates the synthetic versatility of quinone-catalyzed oxidative C–C bond cleavage.
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Date
2017-12-28
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Beilstein-Institut
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Liu_2017.pdf
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Catalysis, Deformylation, Organic synthesis, Organocatalysis
Citation
Liu, X., Phan, J. H., Haugeberg, B. J., Londhe, S. S., & Clift, M. D. (2017). Quinone-catalyzed oxidative deformylation: synthesis of imines from amino alcohols. Beilstein Journal of Organic Chemistry, 13, 2895–2901. http://doi.org/10.3762/bjoc.13.282