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Lewis acid-catalyzed diastereoselective hydroarylation of benzylidene malonic esters

Duan, Shaofeng
; 
Jana, Ranjan
; 
Tunge, Jon A.
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Abstract
Herein we report that simple Lewis acids catalyze the hydroarylation of benzylidene malonates with phenols. Ultimately, 3,4-disubstituted dihydrocoumarins are obtained via a hydroarylation-lactonization sequence. Moreover, the dihydrocoumarins are formed with a high degree of diastereoselectivity favoring the trans stereoisomer.
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Date
2009-06-19
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American Chemical Society
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Chemistry Scholarly Works
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Duan, S., Jana, R., & Tunge, J. A. (2009). Lewis acid-catalyzed diastereoselective hydroarylation of benzylidene malonic esters. The Journal of Organic Chemistry, 74(12), 4612–4614. http://doi.org/10.1021/jo900367g
URI
https://hdl.handle.net/1808/23640
DOI
10.1021/jo900367g
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